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PPSC Chemistry Part I Physical Chemistry Online Test MCQs With Answers
Question # 1
The phase rule was deduced by
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Gibbs
Thomson
Troution
Henry
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Question # 2
Which of the following molecules have centre of symmetry.
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H2O
HCl
CO2
H2SO4
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Question # 3
Which of the following statement is not true with respect to photo chemical reactions.
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These take place in the presence of light
Free energy of these reactions may be positive or negative
Light intensity affect these reactions
Temperature has significant affect n rate of these reactions
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Question # 4
The oxidation Number of I in HIO4 is.
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+6
+ 7
+ 3
+ 14
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Question # 5
The glow of the yellow phosphorous as a result of slow oxidation in air is called.
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Chemiluminescene
Luminescence
Biolumineacence
Photolysis
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Question # 6
If for a solution of an electrolyte. It is the transport number of the cation, then the transport number of the anion I, is equal to
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t/2
1 - t+
1 + t+
(i -t) /2
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Question # 7
The entropy of the universe
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Tends towards a maximum
Tend towards a maximum
Tends to be zero
Remains constatn
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Question # 8
Which of the following specie is stronger acid than formic acid, HCOOH, in aqueous solution.
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CH3COOH
NH+4
H2SO-3
H4P2O7
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Question # 9
The temperature of which the compound melts into a liquid to the same composition as the solid is called the
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Congruent melting point
Incongruent melting point
Peritectic temperatures
Metastable point
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Question # 10
Which law of thermodynamics helps in calculating the absolute entropies of varies substances.
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Zeroth law
1st law
Second law
Third Law
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Question # 11
Which of the following statement is not related with high quantum yield reasons.
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Formation of reactive intermediates which may act as catalyst
The active molecules may collide with other molecules and activates these molecules.
The reaction may be exothermic and heat evolve may activate other molecule
The primary photo chemical process may be reversed
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Question # 12
The kinetics of the decomposition of ammonia on the tungsten surface follows
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Zero order
First order
Second order
Third order
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Question # 13
For assciated liquids, the value of d/M n x 10
8
should be (where d is the density, M is the molar mass and n is the coefficient of viscosity)
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Zero
Infinte
Higher than 70
Less than 70
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Question # 14
Visible light is just a portion of radiation emitted by atoms.Which of the following statements is not related with visible light.
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visible light is electromagnetic in nature.
It travels with the speed of light
It is a mass
The wave number of light is directly proportional to its wave length.
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Question # 15
The azimuth or angular quantum number (i) determines the number of sob shells in a given shall. the allowed values of l for a given value ffor n are.
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1.2.3.......................
1,2,3 ..................(n-1)
0.1.2.3................(n-1)
2,4,6,..............(n-2)
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Question # 16
Which of the following statements is not correct regarding the structure of DNA.
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It has a double helix structure.
There are hydrogen bonds in its structure
Unlike RNA there is no fixed ratio of bases in DNA
The code for protein synthesis is given by the sequence of bases in DNA
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Question # 17
Wlhich of the following can act as a protective colloid
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Gelatin
Silica gel
Oil in water emulsion
All three
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Question # 18
The reverse of photo chemical reaction is called.
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Phosphorescence
Chemiluminescence
Fluorescence
Photscnaitization
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Question # 19
The particle would be stationary in a lattice only at.
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273 K
0 K
298 K
373 K
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Question # 20
The relative lowering of vapour pressure of a solution on the addition of non -volatile solute.
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Is equal to the mole fraction of solute
Is equal to the sum of the mole fraction of the solute and solvent
Depends upon the nature of the solute
Depends upon the mole fraction of the solvent
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Question # 21
Which of the following statement is not correct regarding the constant R . and in ideal gas equation PV= nRT
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Its value in independent of temperature
Its value is independent of pressure
In SI Units its value is 8.314 K
-1
mol
-1
It is called the universal gas constant per molecule.
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