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PPSC Chemistry Part I Physical Chemistry Online Test MCQs With Answers
Question # 1
The Lambert beer law states that
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Transmission is directly proportional to path length
Transmission is directly proportional to concentration
Absorbance is inversely proportional to transmission
Absorbance is directly proportional to concentration.
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Question # 2
'A line, a point or a plane about which a symmetry operation is performed, is known as.
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Symmetry operation
Symmetry element
Reflection
Inversion
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Question # 3
The point group of XeOF4 is.
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C6v
C4h
D4h
D2h
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Question # 4
The blue colour of CuSO4 disappears on adding Zn granules to it . it is because of .
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Oxidation of Cu atom
Oxidation of Zn
2+
Oxidation Cu
2+
Oxidation of Zn
2+
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Question # 5
Which of the following symmetry element leaves the molecule or an object unchanged.
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Proper rotation
Improper rotation
Inversion axis
Identity
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Question # 6
Layer of the C -atom in graphite are hold together by
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Covalent bonds
Free electrons
Ionic bond
Van Dar Waals forces
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Question # 7
Which of the following reactions does not take place with light radiation.
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Oxidation
Reduction
Polymerization
Double displacement
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Question # 8
According to the Grothus -Draper law
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Only absorbed light is effective in producing photo chemical changes
Only light between certain wavelengths
Light is effective only for photo chemical reactions is solution
The light absorbed in proportional to its intensity
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Question # 9
The pKa of acetic acid is 4.74 which implies that.
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pH of 1N solution is 4.74
At pH 4.74 the dissociation of acetic acid is maximum
At pH 4.74 half of the acetic acid molecules are dissociated in the solution.
At pH 4.74 the dissociation of acetic acid is minimum.
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Question # 10
Any property whose magnitude is independent of the amount of substance present is called a/an
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Extensive property
Colligative property
Structural propety
Intensive property
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Question # 11
During reaction of copper with aqueous solution of silver nitrate
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Silver atoms are reduced
Cu2+ ions are reduced
Silver ions are reduced
No
3
ions are reduced
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Question # 12
When a strong beam of light is passed through a colloidal solution, the light will
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Be reflected
Be scattered
Pass unchanged
Be dispersed
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Question # 13
The rate at which a substance reacts depends on its.
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Molecular mass
Active mass
Equivalent mass
Molar mass
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Question # 14
Which of the following methods gives the number average molecular weight of a polymer.
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Light scattering method
Osmotic method
Sedimentation equilibrium method
Viscosity method
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Question # 15
The value of an Einstein
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Is independent of wavelength
Decrease with increase in wavelength
Increase with increase in wavelength
Depends on the temperature of the absorbing system
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Question # 16
Which of the following statement is not related to collision theory.
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Molecules must collide with each other to do a chemical reaction
Molecules must posses a minimum amount of energy
Molecules must have proper orientation
Collision theory is applicable to liquid only.
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Question # 17
In statistical mechanics, there exists a function which contains all the information about a macroscopic system. This function is known as.
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Eigen function
Wave function
Partition function
Distribution function
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Question # 18
Which of the following statement is not related with high quantum yield reasons.
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Formation of reactive intermediates which may act as catalyst
The active molecules may collide with other molecules and activates these molecules.
The reaction may be exothermic and heat evolve may activate other molecule
The primary photo chemical process may be reversed
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Question # 19
The number of formula weight of the solute dissolved per dm3 of the solution is called.
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Mole fraction
Normality
Formality
Molaiity
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Question # 20
Which of the following expression is correct.
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C = n/RT
C = RT/n
RT = Cn
Cn = 1/RT
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Question # 21
The temperate of a gas below which only the gas cools when allowed to expand is know as.
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Inversion temperature
Ideal temperature
Critical temperature
Joule Thomaon temperatu4re
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