1 |
If the energy of the activated complex lies close to energy of reactants, it means that reaction is |
Slow
Exothermic
Endothermic
Exothermic and fast
|
2 |
By increasing the concentration of reactants, the rate of reaction |
Decreases
Increases
Remains constant
Not predicted
|
3 |
The increase in reaction rate as a result of increase in temperature from 10K to 90K is |
512
256
400
112
|
4 |
For a chemical reaction to occur |
The vessel shall be open
Reacting molecules should have less energy than Ea at time of collision
Reacting molecules must be properly oriented and energy more than or equal to Ea
The reacting molecules must not collide with each other
|
5 |
Which of the following reactions are usually slow? |
Neutralization of acids and bases
Displacement Reactions
Organic substitution reaction
Free radical reactions
|
6 |
Rate of which reaction increases with temperature? |
Exothermic and endothermic reactions
Endothermic reactions
Exothermic reactions
None of these
|
7 |
In which of the following techniques rate of reaction is directly related with number ofions |
Spectrometry
Dilatometric method
Conductometric method
Refractometric method
|
8 |
For a chemical reaction which can never be a fractional no |
order
molecularity
half-life
rate constant
|
9 |
If the rate of the reaction is equal to the rate constant, the order of the reaction is |
3
1
0
2
|
10 |
If the reaction "P+Q→R+S' is deseribed as being of zero order with respect to P, it means that |
P is catalyst in this reaction
P molecules do not possess sufficient energy to react
The concentration of P does not change during the reaction
The rate of reaction is independent of the concentration of P
|
11 |
For reaction of methane and chlorine light is not available then |
Reaction will take place rapidly
No Reaction take place
Reaction occurs at double the rate
May all cases occur
|
12 |
Which of the following statement about the order of reaction is true? |
The order of reaction can only be determined by experiment
a second order reaction is also bimolecular
The order of reaction is always non-zero
The order of reaction increases with increasing temperature
|
13 |
The reaction takes place among the molecules when they have: |
Activation energy
Properly oriented
Concentrated
Activation energy and proper orientation
|
14 |
Half-lives required to convert 100% reactant to produet for a first order reaction are |
10
1000
100
Infinity
|
15 |
Doubling the pressure in a liquid phase reaction |
Will double the rex
Will increase the rex
Will decrease the rex
Will not alter the concentration of reactant
|
16 |
When the concentration of reactants is taken as unity the rate of reaction is equal to |
average rate
concentratian of reactant
instantaneous rate
specific rate constant
|
17 |
Higher the surface area available for reaction |
slower the reaction
faster the reaction
constant the reaction
lower the Ea
|
18 |
Amount of product formed increases with time, this statement is true for reactions-------with kinetics |
1s order
3rd order
zero order
Any order
|
19 |
All the Hydrolytic reactions are |
First order
Second order
Third order
pseudo-first order
|
20 |
The radioactive disintegration of 238U92 is |
First order
Second order
Third order
Zero order
|