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MDCAT Chemistry Chapter 13 Fundamental principles of organic chemistry Online Test MCQs With Answers
Question # 1
Which of the following is electrophile for alkylation?
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NO+2
SO3
R+
Both a & b
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Question # 2
Addition of unsymmetrical reagent to an unsymmetrical alkene is governed by
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Cannizzaro's Reaction
Aldol Condensation
Kirchhoff Rule
Markownikov's Rule
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Question # 3
A compound that has a nucleophilic carbon?
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C2H2
C2H4
C3H8
C6H6
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Question # 4
2,5-dimethyl-1-hexene has
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Two sp2 hybridized carbons
Six sp2 hybrid carbons
Two double bonds
Four pi electrons
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Question # 5
2-Propenol, on rearrangement, yields
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Propanal
Propanone
2-propano
Both A and B
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Question # 6
Aniline is the derivative of the benzene containing the
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Hydroxyl group
Amino group
Amido group
Imido group
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Question # 7
Ethene is produced from ethyl chloride by reacting with alcoholic KOH. The process is called
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Hydrogenation
Dehydrogenation
Dehydrohalogenation
Oxidation
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Question # 8
Active sulphonating agent during sulphonation of benzene is
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SO2
SO3
SO3H
SO3+
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Question # 9
Acetylide can give back ethyne upon treatment with
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water
strong base
dil. Acid
weak base
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Question # 10
Substituted phenyl group are called
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Arene groups
Alkyl groups
Aryl groups
Acyl groups
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Question # 11
Which one of the following is a powerful electrophile used to attack on the electrons of benzene ring?
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FeCl2
Cl+
FeCl-4
Cl2
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Question # 12
Which of the following is not an electrophilic substitutional reaction of benzene?
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Free radical chlorination of benzene
Friedel Craft alkylation
Sulphonation
Nitration
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Question # 13
When 1-butene reacts with bromine, the product formed will be
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1, 3-dihydroxy butane
But-1, 2-diol
1, 3-dihydroxy butan-diol
1,2-dibromo butane
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Question # 14
Baever's reagent is misture of
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HCI& ZnCl
Ageous bromine
Alkaline KMn4
Mix of Br2&KMnO4
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Question # 15
Naphthalene has two fused aromatic ring of carbon atom the molecular formula
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C10H8
C10H14
C10H10
C12H12
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Question # 16
Dehydrohalogenation of alkyl halides happens in the presence of
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Pd
Ni
Zn
KOH/alcohol
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Question # 17
The reaction of alkyl halide in the presence of alcoholic KOH is
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Substitution
Addition
Acid-base
Elimination
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Question # 18
Ethylene polymerizes at 100 atm pressure and 400 °C to give
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Polybenzene
Polypropylene
Polyalcohol
Polyethylene
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Question # 19
The angle between the unhybridized 2pz orbital and the three sp2 hybrid orbitals in ethene is
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180°
120°
90°
60°
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Question # 20
Ethane when completely halogenated in excess of chiorine can form
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Hexachloroethane
Dichloroethane
Pentachloroethane
1.1.2.2-terachloroethane
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Question # 21
Among the following the polycyclic aromatic compound is
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Styrene
Naphthalene
Toluene
Acetophenone
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Question # 22
Glyoxal molecule has?
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two carbonyl groups
One aldehydic and one carbonyl group
Two aldehydic groups
Two carboxyl group
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Question # 23
During the nitration of benzene the nitrating agent is
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NO3
NO2+
NO2-
HNO3
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