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MDCAT Chemistry Chapter 13 Fundamental principles of organic chemistry Online Test MCQs With Answers
Question # 1
Acetylide can give back ethyne upon treatment with
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water
strong base
dil. Acid
weak base
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Question # 2
Which of the following tests helps to distinguish between alkyne and alkene?
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Lucas test
Tollen's reagent test
Baeyer's test
Fehling's solution test
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Question # 3
Glyoxal molecule has?
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two carbonyl groups
One aldehydic and one carbonyl group
Two aldehydic groups
Two carboxyl group
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Question # 4
2-Propenol, on rearrangement, yields
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Propanal
Propanone
2-propano
Both A and B
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Question # 5
Which of the following is not an electrophilic substitutional reaction of benzene?
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Free radical chlorination of benzene
Friedel Craft alkylation
Sulphonation
Nitration
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Question # 6
A compound that has a nucleophilic carbon?
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C2H2
C2H4
C3H8
C6H6
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Question # 7
Substituted phenyl group are called
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Arene groups
Alkyl groups
Aryl groups
Acyl groups
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Question # 8
The reaction that generates an ionic bond is
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Halogenation of ethene
polymerization of ethene
Hydrogenation of ethyne
Reaction of ethyne withs sodamide
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Question # 9
The origin ofacidic nature of alkyne is?
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small size of C
Small size of H
polarity of triple bond
sp hybridization
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Question # 10
Benzene cannot undergo the ------- directly
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Substitution reaction
Addition reaction
Oxidation reaction
Elimination reaction
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Question # 11
Among the following the polycyclic aromatic compound is
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Styrene
Naphthalene
Toluene
Acetophenone
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Question # 12
The pi-electrons in the styrene are
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13
10
8
6
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Question # 13
Ethane when completely halogenated in excess of chiorine can form
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Hexachloroethane
Dichloroethane
Pentachloroethane
1.1.2.2-terachloroethane
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Question # 14
Active sulphonating agent during sulphonation of benzene is
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SO2
SO3
SO3H
SO3+
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Question # 15
C-H bond length in the benzene is
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0.99A°
1.09A°
1.12A°
1.34A°
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Question # 16
Dehydrohalogenation of alkyl halides happens in the presence of
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Pd
Ni
Zn
KOH/alcohol
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Question # 17
Which one of the following is a powerful electrophile used to attack on the electrons of benzene ring?
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FeCl2
Cl+
FeCl-4
Cl2
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Question # 18
Aniline is the derivative of the benzene containing the
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Hydroxyl group
Amino group
Amido group
Imido group
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Question # 19
The heat of hydrogenation of most of the alkene is about
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120 kJ/mol
100 kJ/mol
140 kJ/mol
105 kJ/mol
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Question # 20
The angle between the unhybridized 2pz orbital and the three sp2 hybrid orbitals in ethene is
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180°
120°
90°
60°
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