1 |
The chemical method used for determination of rate of reaction is |
Spectroscopic
Conductiometric
Refractometric
Titration
|
2 |
|
Zero
253 sec
150 sec
500 sec
|
3 |
In the expression rate = K [A]a[B]bK is |
The order of reaction
The speed of reaction
The specific rate constant
The overall order of reaction
|
4 |
The rate of reaction determined at a given time is called |
Average rate
Instantaneous rate
Specific rate
Overall rate
|
5 |
With the progressive of the reaction the slope of the curve between concentration of product and time |
Gradually becomes more steep
Gradually becomes less steep
No change occurs in slope
None of these occurs
|
6 |
The reaction rate is expressed in the units of |
Mol dm<sup>-3</sup>S<sup>-</sup>
Mol dm<sup>-3</sup>
Mol dm<sup>-3</sup>N<sup>-</sup>
dm<sup>-3</sup>S<sup>-</sup>
|
7 |
Addition of solid NaHCO3in water causes ionization of NaCHO3its Ka= 4.7 x 10-1. Then this solution has character |
Acidic
Very weakly basic
Alkaline
Neutral
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8 |
The ionization constant of an acid is expressed in term of the following constant |
Kw
Kn
Ka
Kb
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9 |
A solution having pH = 4 its OH-ion concentration in mole dm-3is |
1.0 x 10<sup>-4</sup>
1.0 x 10<sup>-10</sup>
1.0 x 10<sup>-14</sup>
1 x 10<sup>0</sup>
|
10 |
Which one of the following is not a buffer |
H<sub>2</sub>CO<sub>3</sub>+ NaHCO<sub>3</sub>solution
H<sub>3</sub>PO<sub>4</sub>+ NaH<sub>2</sub>PO<sub>4</sub>solution
Hl + Nal solution
NH<sub>4</sub>OH + NH<sub>4</sub>CI solution
|
11 |
Which one of the following is a buffer |
HCI + NaCI solution
CH<sub>3</sub>COOH + CH<sub>3</sub>COONH<sub>4</sub>solution
H<sub>2</sub>SO<sub>4</sub>+ CaSO<sub>4</sub>solution
CH<sub>3</sub>COOH + CH<sub>3</sub>COONa
|
12 |
Base buffer solution can be prepared by mixing |
Weak acid and its salt
Strong acid and its salt with weak base
Weak base and its salt with strong acid
Strong base and its salt with weak acid
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13 |
Whenever a week base is dissolved in water, it give its conjugate acid. similarly a weak acid in water produces its conjugate base. This conjugate acid-base pair concept is stated by |
Law of mass action
Le-charlier's principle
Common ion effect
Lowery Bronsted concept
|
14 |
If the difference of pKa values of the two acids is 2, then |
Acid with smaller pKa is 10 times stronger acid
Acid with greater pKa is 10 times stronger acid
Acid with smaller pKa is 100 times stronger acid
Acid with greater pKa is 100 times stronger acid
|
15 |
0.1 MHCI has pH = 1.0, it is about 100 times stronger than acetic acid. Then pH of acetic acid will be |
0.1
2.0
1.3
3.0
|
16 |
Units of Kw are |
Mole dm<sup>-3</sup>
Mole<sup>2</sup>dm<sup>-3</sup>
Mole<sup>2</sup>dm<sup>-6</sup>
Mole<sup>2</sup>dm<sup>-3</sup>
|
17 |
Which of the following solution have zero pH |
1 M HCI
MH<sub>2</sub>SO<sub>4</sub>
0.1 M HNO<sub>3</sub>
1 M CH<sub>3</sub>COOH
|
18 |
The solubility of KCIO3salt in water is decreased by adding |
NaCIO<sub>3</sub>
NaCI
KCIO<sub>4</sub>
KCI
|
19 |
Kbfor NH4OH is 1.81 x 10-5, then Kavalue of its conjugate base is |
1.81 x 10<sup>+5</sup>
1.81 x 10<sup>-9</sup>
5.5 x 10<sup>-9</sup>
5.5 x 10<sup>-10</sup>
|
20 |
On passing HCI gas through a saturated solution of commercial sodium chloride, pure crystals of NaCI are precipitated due to |
Increase in pH of the solution
Decrease in pH of the solution
Common ion effect
Increase in ionization of NaCl
|
21 |
When a weak acid is dissolved in water or a weak base dissolved in water, then in both cases the conjugate acid base pair is produced. The ionization constants Kaand Kbof a pair are related with each other as |
K<sub>a</sub>= K<sub>b</sub>
K<sub>a</sub>. K<sub>b</sub>= K<sub>w</sub>
K<sub>a</sub>. K<sub>w</sub>= K<sub>b</sub>
K<sub>b</sub>. K<sub>w</sub>= K<sub>a</sub>
|
22 |
Kavalue of HF acid is 6.7 x 10-15the acid is a |
Weak acid
Moderately strong acid
Strong acid
Very weak acid
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23 |
In 1000 molecules of 0.001 M acetic acid the number of H+ions is 12.6, then its percentage of ionization is |
1.33%
1.26%
12.6
1%
|
24 |
Acetic acid is 1.33% ionized, In 1000 molecules of 0.1 M acetic acid the number of H+ions is |
1.33
13.3
1.33
1
|
25 |
A solution of NaOH has pH = 13, then concentration of NaOH is |
10<sup>-13</sup>M
10<sup>13</sup>M
10<sup>-1</sup>M
10<sup>+1</sup>M
|
26 |
A solution has pH = 0, its H+ion concentration is |
1 x 10<sup>-14</sup>
1 x 10<sup>14</sup>
1 x 10<sup>1</sup>
1
|
27 |
The pH of 10-3mole dm-3of an aqueous solution of H2SO4is |
3.0
2.7
2.0
1.5
|
28 |
An aqueous solution is neutral when its |
pH = 14
pH = zero
pH = 7
Kw = 10<sup>-7</sup>
|
29 |
The ionic product of H+ions and OH-in water is called ionization constant of water Kw. The value of Kw at 25°C is |
0.11 x 10<sup>-14</sup>
0.30 x 10<sup>-14</sup>
1.0 x 10<sup>-14</sup>
3 x 10<sup>-14</sup>
|
30 |
|
450°C
250°C
850°C
1000°C
|