1 |
Optical rotation method is sued when |
Reaction involve ions
Change of refractive indices
Reactions involving change of optical activity
None of the above
|
2 |
Dilatometric method is used for rate determination when |
Reactions involving change of optical
Reactions involving change of optical activity
Reactions involving small volume change
None of above
|
3 |
Refrectrometric method is used when |
Reactions involving absorption of I.R. or U. V
Reactions involving change of refractive index
Reactions involving ions
Change of optical activity
|
4 |
If a reactant or product of a reaction absorbs radiation, then physical method for determining the rate of reaction is |
Spectrometry
Refractometry
Conductivity measurement
Optical method
|
5 |
To determine the rate of reaction chemically a graphical method is applied. A graph is plotted between the amount or reactant decomposed or product formed against the time. The rate dx/dtat any time is equal to |
k
Tangent<span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 24px; text-align: center; background-color: rgb(255, 255, 224);">θ</span>
1/a, a is initial conc.
1/a<sup>2</sup>
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6 |
The reaction rate is expressed in the units of |
mol dm<sup>-3</sup>S<sup>-</sup>
mol dm<sup>-3</sup>
mol dm<sup>-3</sup>N<sup>-</sup>
dm<sup>-3</sup>S<sup>-</sup>
|
7 |
Value of rate constant k is specific for a reaction, and varies from reaction to reaction. The value of k of a reaction changes with |
Time
Temperature
Concentration of reactants
Order of reaction
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8 |
The unit of rate constant k is the same as that of the rate of reaction in |
First order reaction
Second order reaction
Third order reaction
Zero order reaction
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9 |
|
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10 |
|
Rate is independent of concentration of water since it is in excess
Rate is independent of concentration of ester since it is in exces
Rate depends upon the concentration of acid catalyst added
Rate = k[CH<sub>3</sub>COOC<sub>2</sub>H<sub>5</sub>]<sup>1/2</sup>[H<sub>2</sub>O]<sup>1/2</sup>
|
11 |
When initial concentration of reactants an order of reaction is given, then its half life period can be calculated by the equation |
|
12 |
If initial concentration of the reactants and half life period of the reaction is known, then we can determine |
Average rate of reaction
Order of reaction
Rate constant k
Instantaneous rate
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13 |
If half life period of a reaction is independent of the concentration of the reactants, then the reaction is |
Zero order
First order
Second order
Order is in fraction
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14 |
When the rate of reaction is entirely independent of the conc. of reaction molecules then order of reaction is |
Zero
First
Second
Third
|
15 |
The experimental relationship between a reaction rate and the concentration of reactants is called |
Order or reaction
Rate law
Activated complex
Molecularity
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16 |
|
Rate = k[FeCl<sub>3</sub>] [Kl]<sup>2</sup>
Rate = k[Fe<sup>+3</sup>][Cl<sup>-1</sup>] [Kl]
Rate = k[Fe<sup>+3</sup>] [Cl<sup>-1</sup>][K;]
Rate = k[Kl]<sup>3</sup>[FeCl<sub>3</sub>]°
|
17 |
|
First order
Pseudo first order
Second order
Zero order
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18 |
|
Zero
1
2
1.5
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19 |
The rate of reaction is denoted by |
dc/dp
dc/ac
dc/dT
dc/dt
|
20 |
The sum of the exponents of the conc. terms in the rate equation is called |
Rate of reaction
Order of reaction
Specific rate constant
Average rate
|
21 |
In the hydrolysis of CH3COOC2H5the acid produced is |
Inhibitor
Catalyst
Auto catalyst
None of above
|
22 |
The rate of reaction between two specific time intervals is called |
Instantaneous rate
Average rate
Specific rate
Ordinary rate
|
23 |
The rate of reaction determined at a given time is called |
Average rate
Instantaneous rate
Specific rate
Overall rate
|
24 |
In the rate equation when the concentration of reactants are unity, then rate is equal to |
Instantaneous rate
Average rate
Active mass of products
Specific rate constant
|
25 |
|
Small change in concentration of product
Small time internal
Co-efficient of the reactant
Co-efficient of the product
|
26 |
The unit of rate of reaction is |
mole dm<sup>-3</sup>
mole Kg<sup>-1</sup>
moles dm<sup>-3</sup>sec<sup>-1</sup>
grams dm<sup>-3</sup>
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27 |
Which statement is not correct |
Enzymes catalyst a specific reaction
Enzymes show catalytic activity at a specific temperature
The catalytic activity of enzymes is stopped if optimum pH is changed
The catalytic activity is poisoned by a co-enzymes
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28 |
A substance which increases the rate of a reaction without being consumed during the reaction is called |
An autocatalyst
A catalyst
A negative catalyst
All of these
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29 |
Factor which slows down the rate of reaction is |
Small size of the particles of the reactant
High temperature of reaction
More concentration of reactant
Lowering the temperature
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30 |
Activation energy is the difference of energy between the energy of the reactant and |
The product
The activated complex
Both a and b
None of these
|