1 |
Compound X has molecular formula C10H14O and is unreactive towards mild oxidising agents. What is the structure of the compound formed by dehydration of X |
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2 |
In its reaction with Na, 1 mol of X gives 1 mol of H2(g). What is X |
CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>OH
(CH<sub>3</sub>)<sub>3</sub>COH
CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CO<sub>2</sub>H
CH<sub>3</sub>CH(OH)CO<sub>2</sub>H
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3 |
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1-bromobutane
2-bromobutane
1-bromo-2-methyl propane
2-bromo-2-methyl propane
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4 |
An organic compound will decolorise dill acidified (aq) KMnO4on warming, but will not decolorise bromine water. What is the compound |
KMnO<sub>4</sub>
Ethanol
Ethane
CH<sub>3</sub>CH<sub>2</sub>Cl
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5 |
Which structure shows a tertiary alcohol |
CH<sub>3</sub>CH<sub>2</sub>OH
(CH<sub>3</sub>)<sub>2</sub>CHOH
(CH<sub>3</sub>)<sub>3</sub>COH
CH<sub>2</sub>OH
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6 |
How many secondary alcoholic groups are present in the structure of glucose OHC CHOH CHOHCH OH CHOH CH2OH |
1
2
3
4
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7 |
What will react differently with the two isomeric pentols, (CH3)3CCH2OH and (CH3)2CH CH2CH2OH |
Acidified (aq) KMnO<sub>4</sub>
Concentrated H<sub>2</sub>SO<sub>4</sub>
PCl
Sodium
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8 |
Which alcohol gives only one oxidation product when wormed with dil acidified K2Cr2O7 |
Butan-1-ol
Butan-2-ol
2-methyl propan-1-ol
2-methyl propan-2-ol
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9 |
How many alcohol (including both structural isomers and stereoisomers) can have the molecular formula C4H10O |
3
4
5
6
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10 |
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NH<sub>3</sub> HCl
KCN in C<sub>2</sub>H<sub>5</sub>OH NaOH
KCN in C<sub>2</sub>H<sub>5</sub>OH HCl
HCN NaOH
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11 |
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Electrophilic substitution
Free radical reduction
Isomerisation
Nucleophilic substitution
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12 |
Which reaction is example of nucleophilic substitution |
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13 |
What is the total number of different chloroethanes, formula C2H6-nCln, where n can be any integer from 1 to 4 |
4
6
7
8
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14 |
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Condensation
Electrophilic substitution
Free radical substitution
Nucleophilic substitution
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15 |
Each of the following compounds is effective as a refrigerant. The release of which one of these causes the greatest depletion of the ozone layer |
CCl<sub>2</sub>F<sub>2</sub>
CH<sub>3</sub>OCH<sub>3</sub>
CH<sub>3</sub>CHF<sub>2</sub>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
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16 |
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF2Cl. |
CHF Cl C FCl
CH Cl CF<sub>2</sub>Cl
CHF CF<sub>2</sub>Cl
C FCl CF<sub>2</sub>Cl
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17 |
What is the total number of different chloroethanes of formula C2H6-nClnpossible (n may be 1 to 6) |
6
8
9
10
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18 |
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Electrophilic addition
Electrophilic substitution
Free radical substitution
Nuclophilic addition
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19 |
Which one of the following is not a nucleophile |
H<sub>2</sub>O
H<sub>2</sub>S
BF<sub>3</sub>
NH<sub>3</sub>
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20 |
Alkyl halides ae considered to be very reactive compounds towards nucleophiles because |
They have an electrophilic carbon
They have an electrophilic carbon and a good leaving group
They have an electrophilic carbon and a bad leaving group
They have a nucleophilic carbon and a good leaving group
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21 |
When CO2is made to react with ethyl magnesium iodide, followed by acid hydrolysis, the product formed is |
Propane
Propanoic acid
Propanal
Propanol
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22 |
Grignard's reagent is |
Alkyl halide
Magnesium halide
Alkyl magnesium halide
Ethereal solution of an alkyl halide
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23 |
When formaldehyde is added to Grignard reagent we get |
Aldehyde
Acetone
Primary alcohol
Secondary alcohol
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24 |
The compounds or species in search of electrons are called |
Elctrophiles
Nucleophile
Nitrities
Bases
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25 |
Thre rate of SN2 reaction depends upon the |
Concentration of alkyl halides
Concentration of nucleophile
Concentration of alkyl halides and nucleophile
None of the above
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26 |
When alkyl halide is heated with aqueous solution of ammonia at 100°C the major product is |
Primary amine
Secondary amine
Tertiary amine
Mixture of amines and salt
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27 |
Which of the following alkyl halides is used as a mathylating agent |
CH<sub>2</sub>H<sub>5</sub>l
CH<sub>3</sub>l
C<sub>2</sub>H<sub>5</sub>Pr
C<sub>2</sub>H<sub>5</sub>Cl
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28 |
During nitration of benzene, the active nitrating agent is |
NO3
NO2+
NO2-
HNO3
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29 |
Amongst the following the compound that can be most readily sulphonated is |
Toluene
Benzene
Nitrobenzene
Chlorobenzene
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30 |
Benzene does not undergo |
Substitution reaction
Addition reaction
Oxidation reaction
Elimination reaction
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