1 |
|
0.02
0.2
50
25
|
2 |
The state of equilibrium refers to |
State of rest
Dynamic state
Stationary state
State of inertness
|
3 |
Two moles of HI was heated in a sealed tube at 440°C till the equilibrium was reached. HI was found to be 22% decomposed. The equilibrium constant for dissociation is |
0.282
0.0796
0.0199
1.99
|
4 |
The avtive mass of 64 g of HI in a two litre flask would be |
2
1
5
0.25
|
5 |
Which of the following factors will favour the reverse reaction in a chemical equilibrium? |
Increase in concentration of one of the reactants
Increase in concentration of one of the products
Removal of one of the products regularly
None of these
|
6 |
|
Favour the formation of N<sub>2</sub>O<sub>4</sub>
Favour the decomposition of N<sub>2</sub>O<sub>4</sub>
Not alter the equilibrium
Stop the reaction
|
7 |
According to Le-Chatelier's principal, adding heat to a solid and liquid in equilibrium will cause the |
Amount of solid to decrease
Amount of liquid to decrease
Temperature to rise
Temperature to fall
|
8 |
|
Equal volumes of N<sub>2</sub>and H<sub>2</sub>are reacting
Equal masses of N<sub>2</sub>and H<sub>2</sub>are reacting
The reaction has stopped
The same amount of ammonia is formed as is decomposed into N<sub>2</sub>and H<sub>2</sub>
|
9 |
|
[A] = [B]
[A] < [B]
[B] = [C]
[A] > [B]
|
10 |
|
Complete conversion of A to B has taken place
Conversion of A to B is only 50% complete
Only 10% conversion of A to B has taken place
The rate of transformation of A to B is just equal to rate of transformation of B to A in the system
|
11 |
The equilibrium constant in a reversible chemical reaction at a given temperature |
Depends on the initial concentration of the reactants
Depends on the concentration of one of the products at equilibrium
Does not depend on the initial concentration of rectants
It is characteristic of the reaction
|
12 |
In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled then the equilibrium constant will |
Also be doubled
Be halved
Becomes one fourth
Remains the same
|
13 |
|
0.60
1.67
0.66
2.6
|
14 |
|
Forward reaction is favoured
Backward reaction is favoured
No effect
None of the above
|
15 |
The bond order in No is 2.5 while that in NO+is 3.Which of the following statements is true for these two species? |
Bond length in NO<sup>+</sup>is greater than in NO
Bond length in unpredictable
Bond length in NO<sup>+</sup>is equal to that in NO
Bond length in NO is greater than in NO<sup>+</sup>
|
16 |
Which carbon is more electronegative? |
sp<sup>3</sup>- hybridized carbon
sp-hybridized carbon
sp<sup>2</sup>-hybridized carbon
always same irrespective of its hybrid state
|
17 |
Maximum hydrogen bonds in water are |
4
3
2
8
|
18 |
In OF2, number of bond pairs and Ione paris of electrons are respectively |
2,6
2,8
2,10
2,9
|
19 |
Which of the following has zero depole-moment? |
CIF
PCl<sub>3</sub>
SiF<sub>4</sub>
CFCl<sub>4</sub>
|
20 |
Number of sigma bonds in P4O10is |
6
7
17
16
|
21 |
The electronegativeities of F,Cl,Br and I are 4.0,3.0,2.8,2.5 respectively.Hydrogen halide with a high percentage of ionic character is |
HF
HCL
HBr
HI
|
22 |
Shape of CIO3is |
Triangular pyramidal
Tetrahedral
Triangular planar
Triangular bipyramidal
|
23 |
Fluorine molecule is formed by |
The axial p-p overlap
The sidewise p-p overlap
The axial s-p overlap
The overlap of two sp<sup>2</sup>hybrid orbitals
|
24 |
The boiling point of heavy water is |
108<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
101.4<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
99<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
110<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
|
25 |
Antibonding MO is formed by |
Addition of atomic orbitals
Substraction of atomic orbitals
Multiplication of atomic orbitals
None of these
|
26 |
The number of antibonding electron pairs in O2-molecular ion on the basis of MOT is |
4
3
2
5
|
27 |
The bond order of individual C - C bond is benzene is |
One
Two
Between one and two
One and two alternately
|
28 |
The shape of gaseous SnCl2is |
Tetrahedral
Linear
Angular
T-shaped
|
29 |
The shape of the molecule SF2Cl2is |
Trigonal bipyradmidal
Cubic
Octahedral
Tetrahedral
|
30 |
The most suitable method of the separation of a mixture of ortho and para-nitrophenol mixed in the ratio of 1: 1 is |
Distrillation
Crystallization
Vapourisation
Colour spectrum
|