1 |
The osmotic pressure of a dilute solution is directly proportional to the |
Diffusion rate of the solute
Ionic concentration
Elevation in boiling point
Flow of solvent from a concentrated to a dilute solution
|
2 |
The vant Hoff factor (1) accounts for |
Degree of solubilisation of solute
The extent of dissolution of solute
The extent of dissolution of solute
The degree of decomposition of solution
|
3 |
Equal volumes of ethylene glycol (molar mass = 62) and water (molar mass = 18) are mixed. The depression in freezing point of water is (given Krof water = 1.86 K mol-1kg and specific gravity of ethylene glycol is 1.11) |
0.003
3.33
0.333
33.3
|
4 |
The weight of pure NaOH required to prepare 250 cm3of 0.1 N solution is |
4 g
1 g
2 g
5 g
|
5 |
50 mL of 10 N H2SO4. 25mL of 12 N Hcl and 40 mL of 5N HNO3are mixed and the volume of the mixture is made 100 mL by adding water. The normality of resulting will be |
1 N
2 N
3 N
9 N
|
6 |
0.5 M of H2SO4is diluted from 1 litre to 10 litre, normality of resulting solution is |
1 N
0.1 N
10 N
11 N
|
7 |
The vapour pressure of two liquids 'p' and 'Q' are 80 and 60 torr respectively. The total vapour pressure of solution obtained by mixing 3 mole of P and 2 mol of Q would be |
140 torr
20 torr
68 torr
72 torr
|
8 |
Ifα us the degree of dissociation of Na2SO4the vant Hoff's factor (1) used for calculating the molecular mass is |
1 +<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α</span>
1 -<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α</span>
1 + 2<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α</span>
1 - 2<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α</span>
|
9 |
The weight of pure NaOH required to prepare 250 cm3of 0.1 N solution is |
4 g
1 g
2 g
5 g
|
10 |
Camphor is often used in molecular mass determination because |
It is solvent for organic substances
It is readily available
It has a very high cryoscopic constant
It is volatile
|
11 |
A solution contains 1.2046 x 1024hydrochloric acid molecules in one dm3of the solution. The strength of the solution is |
6 N
2 N
4 N
8 N
|
12 |
Maximum freezing point falls in |
Camphor
Naphthalene
Benzene
Water
|
13 |
Azeotropic mixture of HCl and water has |
48% HCl
22.2% HCl
36% HCl
20.2% HCl
|
14 |
The ionic strength of a solution containing 0.1 mole/kg of KCl and 0.2 mole/kg of CuSO4is |
0.3
0.6
0.9
0.2
|
15 |
Which of the statements given below concerning properties of solution, describe a colligative effect? |
Boiling point of pure water decreases by the addition of ethanol
Vapour pressure of pure water decreases by the addition of nitric acid
Vapour pressure of pure benzene decreases by the addition of naphthalene
Boiling point of pure benzene increases by the addition of toluene
|
16 |
If liquids A and B form an ideal solution |
The enthalpy of mixing is zero
The entropy of mixing is zero
<div>The free energy of mixing is zero</div>
The free energy as well as the entropy of mixing are each zero
|
17 |
At room temperature, the mole fraction of a solution in 0.25 and the vapour pressure of the solvent is 0.80 atm. Then the lowering of vapour pressure is |
0.75
0.512
0.80
0.0512
|
18 |
When the solute is present in trace quantities the following expression is used |
Gram per million
Milligram percent
Microgram percent
Parts per million
|
19 |
The solubility of a gas in water depends upon |
Nature of the gas
Temperature
Pressure of the gas
All of the above
|
20 |
The depression of freezing point is directly proportional to |
Mole fraction of the solution
Molarity of the solution
Molality of the solution
Molarity of the solvent
|
21 |
The temperature at which the vapour pressure of a liquid becomes equal to external pressure is |
Melting point
Sublimation point
Inversion point
Boiling point
|
22 |
How much of NaOH is required to neutralize 1500 cm3of 0.1 N HCl? |
60 g
6 g
4 g
40 g
|
23 |
Partial pressure of a solution component is directly proportional to its mole fraction. This statement is known as |
Henry's law
Raoult's law
Distribution law
Ostwald's dilution law
|
24 |
Which substances are mixed to form a buffer solution? |
A strong acid and its salt of a strong base
Strong acid and its salt of weak base
Weak acid and its salt of strong base
Weak acid and its salt of weak base
|
25 |
The osmotic pressure of 1 m solution at 27°C is |
2.46 atm
24.6 atm
1.21 atm
12.1 atm
|
26 |
How many g of dibasic acid (mol. wt. 200) should be present in 100 ml of the aqueous solution to give 0.1 Normality? |
1 g
2 g
10 g
20 g
|
27 |
Solutions with same osmotic pressures are called |
Hypertonic
Hypotonic
Isotonic
Normal
|
28 |
The relative lowering of vapour pressure is equal to the mole fraction of the solute, This law is called |
Henry's law
Raoult's law
Ostwald's law
Arrhenius law
|
29 |
Which one of the following is a colligative property? |
Surface tension
Osmotic pressure
Viscosity
Refractive index
|
30 |
Which of the following will have the highest boiling point at 1 atm pressure? |
0.1 M NaCl
0.1 M Sucrose
0.1 M BaCl<sub>2</sub>
0.1 M Glucose
|