1 |
Which of the following has greatest tendency to lose electron? |
F
Fr
S
Be
|
2 |
Which of the following elements is most electronegative? |
Oxygen
Chlorine
Nitrogen
Fluorine
|
3 |
The alkali metal which is liquid at 15°C is |
K
Cs
Na
None
|
4 |
Which of the following pairs are chemically dissimilar? |
Na and K
Ba and Sr
Zr and Hf
Ca and Zn
|
5 |
Variable valency is generally exhibited by |
Normal elements
Transition elements
Metallic elements
None of these
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6 |
Which of the following statements is most appropriate about effective nuclear charge? It depends upon |
The shielding constant
The atomic number
The charge on the nucleus
Both the nuclear charge and the shielding constant
|
7 |
Which of the following represents elements in order of increasing atomic size? |
I, Br, Cl
Na, Mg, C
C, N, O
Li, Na, K
|
8 |
In a hydrogen-oxygen fuel cell, combustion of hydrogen occurs to |
Generate heat
Remove adsorbed oxygen from electrode surfaces
Produce High purity water
Create potential difference between two electrodes
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9 |
In a Galvanic cell, the electrons flow from |
A node to cathode through the solution
Cathode to anode through the external circuit
Cathode to anode through the external circuit
Anode to cathode through the external circuit
|
10 |
Specific conductivity of a solution |
Increases with dilution
Decreases with dilution
Remains unchanged with dilution
Depends on mass of electrolyte
|
11 |
For spontaneity of a cell, which is correct? |
<span style="color: rgb(34, 34, 34); font-family: "Times New Roman"; font-size: 24px; text-align: center; background-color: rgb(255, 255, 248);"><b>Δ</b></span>G = 0,<b style="text-align: center;">Δ</b>E = 0
<b style="text-align: center;">Δ</b>G = -ve ,<b style="text-align: center;">Δ</b>E = 0
<b style="text-align: center;">Δ</b>G = +ve ,<b style="text-align: center;">Δ</b>E = 0
<b style="text-align: center;">Δ</b>G = -ve
|
12 |
The standard e.m.f. of a galvanic cell involving cell reaction with n = 2 is found to be 0.2965 V at 25°C. The equilibrium constant of the reaction would be |
1.0 x 10<sup>10</sup>
2.0 x 10<sup>11</sup>
4.0 x 10<sup>12</sup>
1.0 x 10<sup>2</sup>
|
13 |
An electric current is passed through silver nitrate solution using silver electrodes.10.79 g of silver was found to be deposited on the cathode if the same amount of electricity is passed through copper sulphate solution using copper electrodes, the weight of copper deposited on the cathode is |
6.4 g
2.3 g
128.8 g
3.2 g
|
14 |
An electric current is passed through silver voltameter connected to a water voltmeter. The cathode of the silver voltameter is 0.108 g more at the end of the electrolysis. The volume of oxygen evolved at STP is |
56 cm<sup>3</sup>
550 cm<sup>3</sup>
5.6 cm<sup>3</sup>
11.2 cm<sup>3</sup>
|
15 |
If the standard electrode potential of CU2+/Cu electrode is 0.34 V, what is the electrode potential of 0.01 M concentration of Cu2+? (T=298) |
0.399 V
0.281 V
0.222 V
0.176 V
|
16 |
Which of the following (1 M) conducts more electricity? |
Sulphuric acid
Boric acid
Nitric acid
Phosphorus acid
|
17 |
Time required to deposit one millimole of aluminium metal by the passage of 9.65 amperes through molten electrolyte containing aluminium ion is |
30 s
10 s
30,000 s
10,000 s
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18 |
Same amount of electric current is passed through solutions of AgNO3and HCl. If 1.08 g of silver is obtained in the first case, the amount of hydrogen liberated as S.T.P in the second case is |
112 cm<sup>3</sup>
22400 cm<sup>3</sup>
224 cm<sup>3</sup>
1.008 g
|
19 |
Standard reduction electrode potential of three metals A, B and C are erespectively + 0.05 V, -3.0 and -1.2V. The reducting power of |
B > C > A
A > B > C
C > B > A
A > C > B
|
20 |
When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be |
1.08 g
10.8 g
21.6 g
108 g
|
21 |
The unit of specific conductivity is |
Ohm cm<sup>-1</sup>
Ohm cm<sup>-2</sup>
Ohm<sup>-1</sup>cm
Ohm<sup>-1</sup>cm<sup>-1</sup>
|
22 |
Corrosion is basically a |
Altered reaction in presence of H<sub>2</sub>O
Electrochemical phenomenon
Interaction
Union between two light metals and a heavy metal
|
23 |
In electrolysis of NaCl when Pt electrode is taken then H2is liberated at cathode while with Hg cathode it forms sodium amalgam |
Hg is more inert than Pt
More voltage is required to deduce H<sup>+</sup>at Hg than Pt
Na is dissolved in Hg while it does not dissolve in Pt
Conc. of H<sup>+</sup>ions is larger when Pt electrode is taken
|
24 |
A smuggler could not carry gold by chemically depositing iron on the gold surface since |
Gold is denser
Iron rusts
Gold has higher reduction potential then iron
Gold has lower reduction potential then iron
|
25 |
The reference electrode is made by using |
ZnCl<sub>2</sub>
CuSO<sub>4</sub>
HgCl<sub>2</sub>
Hg<sub>2</sub>Cl<sub>2</sub>
|
26 |
The standard EMF of Daniel cell is 1.10 volt. The maximum electrical work obtained from the Daniel cell is |
212.3 kJ
175.4 kJ
106.15 kJ
53.07 kJ
|
27 |
The equivalent conductivity of 0.1 M week acid is 100 times less than at infinite dilution. The degree of dissociation is |
100
10
0.01
0.001
|
28 |
Calculate the amount of charge flowing in 2 minute in a wire of resistance 10Ωwhen a potential difference of 20 V is applied |
120 C
240 C
20 C
4 C
|
29 |
The specific conductance of 0.1 M NaCl solution is 1.06 x 10-2ohm-1mol-1. Its molar conductance in ohm-1cm2mol-1is |
1.06 x 10<sup>2</sup>
1.06 x 10<sup>3</sup>
1.06 x 10<sup>4</sup>
53
|
30 |
Best way to prevent rusting of iron is by |
Making iron cathode
Putting it in saline water
Both of these
None of these
|