Question # 1

Water shows maximum density at

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4°C

0°C

100°C

-4°C

Hydrochloric acid available in the laboratory is 36% w/w. The density of HCl solution is 1.19 g cm^-3. The molarity of HCl solution is

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10.23 moles dm^-3

11.55 moles dm^-3

11.73 moles dm^-3

12.67 moles dm^-3

A solution consisting of 92 grams ethyl alcohol (C₂H₅OH) 96 grams methyl alcohol (CH₃OH) 90 grams water the mole fraction and mole percent of methyl alcohol is

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0.3. 30%

0.2, 30%

0.5, 30%

0.2, 20%

Which statement is not true. A solution is a homogeneous mixture of

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Two ionic substance like NaCl and HCl

Two molecular substances sugar and water

A solute and a solvent 1% NaHCO₃in water

NaCl and sand

The molarity of toluene solution in benzene is 0.22 if 5 grams of toluene dissolved, then mass of benzene is grams is

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267

260

240

247

What happens when isotonic solution of A (mol.wt.342) and B (mol.wt 60) are put in to communication through semipermeable membrane?

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Transference of solvent from solution A to that of B take place

Transference of solvent from solution B to that of A takes place

No transference of solvent from solution A to that of B takes place

Change in temperature of solutions takes place

An azeotropic mixture of two liquids boils at a lower temperature than either of them when lower temperature

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It is saturated

it shows positive deviation from Raoult's law

It shows negative deviation form Raoult's law

It is metastable

Precipitation will occur until the ionic product becomes

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Equal to K_sp

Lesser than K_sp

Greater than K_sp

None of these

The molarity of the solution containing x grams (NH₄)₂SO₄in 500 cm³of the solution is 0.6 what is x

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39.6

45.1

40.5

42.7

Solution may have units

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Molarity

Molality

Mole fraction

All of them

Equal volumes of 0.1 M AgNO₃and 0.2 M NaCl are mixed. The concentration of NO^-₃ions in the mixture will be

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0.1 M

0.05 M

0.2 M

0.15 M

Vant Hoff's factor of Ca(NO₃)₂is

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1

2

3

4

The freezing point of 1 molal NaCl solution assuming NaCl to be 100% dissociated in water in

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-1.86°C

-3.72°C

+1.86°C

+3.72°C

Which of the statements given below concerning properties of solution, describe a colligative effect?

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Boiling point of pure water decreases by the addition of ethanol

Vapour pressure of pure water decreases by the addition of nitric acid

Vapour pressure of pure benzene decreases by the addition of naphthalene

Boiling point of pure benzene increases by the addition of toluene

17.1 grams sucrose (C₁₂H₂₂O₁₁) dissolved in 250 cm³of solution. This has molarity

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0.1 M

0.2 M

0.01 M

0.02 M

Mixture of alcohol and water can be separated by

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Solvent extraction techniques

Crystallization

Precipitation and filtration

Fractional distillation

The substance which contains the water of crystallization is called

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Hydrated

Solvated

Crystal

None

Which is not a colligative property?

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Osmotic pressure

Lowering of vapour pressure

Depression of freezing point

Elevation of boiling point

Solubility cure of Na₂SO₄10H₂shows

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Constant increase of solubility

Constant decreases of solubility

Discontinuously solubility wit temperature

None of above

The depression of freezing point is directly proportional to

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Mole fraction of the solution

Molarity of the solution

Molality of the solution

Molarity of the solvent

Equal volumes of ethylene glycol (molar mass = 62) and water (molar mass = 18) are mixed. The depression in freezing point of water is (given K_rof water = 1.86 K mol^-1kg and specific gravity of ethylene glycol is 1.11)

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0.003

3.33

0.333

33.3

50 cm³of 0.05 molar nrea (N₂H₄CO) solution has % W/N concentration

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6%

3%

0.3 %

0.6 %

Compared to a 1.0M aqueous solution of calcium chloride will have

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The same freezing and boiling point

A lower freezing point and lower boiling point

A lower freezing point and higher boiling point

A higher freezing point and higher boiling point

0.5 M of H₂SO₄is diluted from 1 litre to 10 litre, normality of resulting solution is

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1 N

0.1 N

10 N

11 N

Solution which distill without change in composition or temperature are called

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Amorphous

Azeotropic mixture

Ideal

Super saturated

Which one of the following is a colligative property?

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Surface tension

Osmotic pressure

Viscosity

Refractive index

Number of moles of the solute dissolved per dm³of the solution is knows as

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Molarity

Formality

%age

None of these

The number of moles of NH₄CI dissolved in 500 cm³of its 15%, W/N solution is

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1 mole

1.4 mole

2.0 mole

2.4 mole

The solutions of NaCl and KCl are prepared separately by dissolving same amount of solute in water, which of the following statements is true fro these solutions ?

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KCl solution will have higher boiling point than NaCl solution.

Both the solutions have same boiling points.

KCl and NaCl solutions possess same vapour pressure.

KCl solution possesses lower freezing point than NaCl solution.

According to Raoult's law

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Relative lowering of V.P. is equal to mole fraction of solute

The lowering of V.P. is directly proportional to mole fraction of solute

V.P. of solvent above solution is equal to product of V.P. of pure solvent and mole fraction of solvent ins solution

All of the above

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