1 |
At certain temperature, 50% of HI is dissociated into H2and I2the equilibrium constant is |
1.0
3.0
0.5
0.25
|
2 |
|
Total pressure
Amount of A<sub>2</sub>and B<sub>2</sub>
Temperature
Catalyst
|
3 |
In an exothermic reaction, a 10° rise in temperature will |
Decrease the value of equilibrium constant
Double the value of K<sub>c</sub>
Not produce any change in K<sub>c</sub>
Produce some increase in K<sub>c</sub>
|
4 |
In which of the following cases, the reaction goes farthest to completion |
K = 10<sup>3</sup>
K = 10<sup>-2</sup>
K = 10
K = 10<sup>0</sup>
|
5 |
|
0.02
0.2
50
25
|
6 |
The state of equilibrium refers to |
State of rest
Dynamic state
Stationary state
State of inertness
|
7 |
Two moles of HI was heated in a sealed tube at 440°C till the equilibrium was reached. HI was found to be 22% decomposed. The equilibrium constant for dissociation is |
0.282
0.0796
0.0199
1.99
|
8 |
The avtive mass of 64 g of HI in a two litre flask would be |
2
1
5
0.25
|
9 |
Which of the following factors will favour the reverse reaction in a chemical equilibrium? |
Increase in concentration of one of the reactants
Increase in concentration of one of the products
Removal of one of the products regularly
None of these
|
10 |
|
Favour the formation of N<sub>2</sub>O<sub>4</sub>
Favour the decomposition of N<sub>2</sub>O<sub>4</sub>
Not alter the equilibrium
Stop the reaction
|
11 |
According to Le-Chatelier's principal, adding heat to a solid and liquid in equilibrium will cause the |
Amount of solid to decrease
Amount of liquid to decrease
Temperature to rise
Temperature to fall
|
12 |
|
Equal volumes of N<sub>2</sub>and H<sub>2</sub>are reacting
Equal masses of N<sub>2</sub>and H<sub>2</sub>are reacting
The reaction has stopped
The same amount of ammonia is formed as is decomposed into N<sub>2</sub>and H<sub>2</sub>
|
13 |
|
[A] = [B]
[A] < [B]
[B] = [C]
[A] > [B]
|
14 |
|
Complete conversion of A to B has taken place
Conversion of A to B is only 50% complete
Only 10% conversion of A to B has taken place
The rate of transformation of A to B is just equal to rate of transformation of B to A in the system
|
15 |
The equilibrium constant in a reversible chemical reaction at a given temperature |
Depends on the initial concentration of the reactants
Depends on the concentration of one of the products at equilibrium
Does not depend on the initial concentration of rectants
It is characteristic of the reaction
|
16 |
In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled then the equilibrium constant will |
Also be doubled
Be halved
Becomes one fourth
Remains the same
|
17 |
|
0.60
1.67
0.66
2.6
|
18 |
|
Forward reaction is favoured
Backward reaction is favoured
No effect
None of the above
|
19 |
The solubility product of Ca(OH)2is 6.5 x 10-6. The concentration of OH-ions is |
1.175 x 10<sup>-2</sup>
2.35 x 10<sup>-2</sup>
3.25 x 10<sup>-3</sup>
3.25 x 10<sup>-4</sup>
|
20 |
The solubility of PbF2is 2.6 x 10-3mole dm-3 then its solubility product is |
2.6 x 10<sup>-3</sup>
6.76 x 10<sup>-6</sup>
5.2 x 10<sup>-6</sup>
7.0 x 10<sup>-8</sup>
|
21 |
Kspvalue for PbSO4= 1.8 x 10-8mole2dm-6. The maximum concentration of Pb++ions is |
1.34 x 10<sup>-4</sup>mole dm<sup>-3</sup>
1.8 x 10<sup>-4</sup>
3.6 x 10<sup>-16</sup>mole dm<sup>-3</sup>
1.0 x 10<sup>-8</sup>mole dm<sup>-3</sup>
|
22 |
The solubility product of AgCl is 2.0 x 10-10mole 2dm-6. The maximum concentration of Ag+ions in the solution is |
2.0 x 10<sup>-10</sup>mole dm<sup>-3</sup>
1.41 x 10<sup>-5</sup>mole dm<sup>-3</sup>
1.0 x 10<sup>-10</sup>
4.0 x 10<sup>-20</sup>mole dm<sup>-3</sup>
|
23 |
Product of concentration of ions raised to the power equal to the co-efficient of ions in balanced equation for saturated solution of a salt is called |
Ionic product
Equilibrium constant K<sub>c</sub>
K<sub>w</sub>
Solubility product (K<sub>sp</sub>)
|
24 |
Buffers having pH less than 7 are made |
Mixture of weak acid + salt of it with strong base
Mixture of weak acid + salt of it with weak base
Mixture of weak base + salt of it with strong acid
Mixture of weak base + salt of it with weak base
|
25 |
The relation between Kc and Kp is |
|
26 |
pH of the human blood which is essentially maintained constant due to carbonates, biocarbonates, phosphates etc., is |
7.00
7.25
7.35
7.47
|
27 |
A buffer solution of 0.1 molar HCOOH and 0.1 molar HCCONa has pH = 3.78 To is 0.01 molar HCl is added, then pH of the buffer solution becomes |
2.78
4.78
3.78
3.70
|
28 |
If pH of buffer of 1 mole dm-3of HCOOH + 0.1 mole dm-3HCOONa having pKa = 3.78 is |
1.78
2.78
3.78
4.78
|
29 |
pH of 0.1 molar HCl solution is |
1
zero
13
14
|
30 |
A buffer of a 0.09 molar acetic acid and 0.11 molar sodium acetate has pH = 4.83. If 0.01 mole NaOH in 1 dm3of the buffer solution is added, then pH of the buffer becomes |
4.74
4.92
5.0
4.0
|