1 |
The bond order in No is 2.5 while that in NO+is 3.Which of the following statements is true for these two species? |
Bond length in NO<sup>+</sup>is greater than in NO
Bond length in unpredictable
Bond length in NO<sup>+</sup>is equal to that in NO
Bond length in NO is greater than in NO<sup>+</sup>
|
2 |
Which carbon is more electronegative? |
sp<sup>3</sup>- hybridized carbon
sp-hybridized carbon
sp<sup>2</sup>-hybridized carbon
always same irrespective of its hybrid state
|
3 |
Maximum hydrogen bonds in water are |
4
3
2
8
|
4 |
In OF2, number of bond pairs and Ione paris of electrons are respectively |
2,6
2,8
2,10
2,9
|
5 |
Which of the following has zero depole-moment? |
CIF
PCl<sub>3</sub>
SiF<sub>4</sub>
CFCl<sub>4</sub>
|
6 |
Number of sigma bonds in P4O10is |
6
7
17
16
|
7 |
The electronegativeities of F,Cl,Br and I are 4.0,3.0,2.8,2.5 respectively.Hydrogen halide with a high percentage of ionic character is |
HF
HCL
HBr
HI
|
8 |
Shape of CIO3is |
Triangular pyramidal
Tetrahedral
Triangular planar
Triangular bipyramidal
|
9 |
Fluorine molecule is formed by |
The axial p-p overlap
The sidewise p-p overlap
The axial s-p overlap
The overlap of two sp<sup>2</sup>hybrid orbitals
|
10 |
The boiling point of heavy water is |
108<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
101.4<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
99<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
110<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°C</span>
|
11 |
Antibonding MO is formed by |
Addition of atomic orbitals
Substraction of atomic orbitals
Multiplication of atomic orbitals
None of these
|
12 |
The number of antibonding electron pairs in O2-molecular ion on the basis of MOT is |
4
3
2
5
|
13 |
The bond order of individual C - C bond is benzene is |
One
Two
Between one and two
One and two alternately
|
14 |
The shape of gaseous SnCl2is |
Tetrahedral
Linear
Angular
T-shaped
|
15 |
The shape of the molecule SF2Cl2is |
Trigonal bipyradmidal
Cubic
Octahedral
Tetrahedral
|
16 |
The most suitable method of the separation of a mixture of ortho and para-nitrophenol mixed in the ratio of 1: 1 is |
Distrillation
Crystallization
Vapourisation
Colour spectrum
|
17 |
According to VSEPR theory, the shape of the water molecule is |
Octahedral
Distorted tetrahedral
Planar triangle
Linear
|
18 |
Which of the following hydrides has the lowest boiling point? |
H<sub>2</sub>O
H<sub>2</sub>S
H<sub>2</sub>S3
H<sub>2</sub>Te
|
19 |
The shape of CIO-3according to valence shell electron pair repulsion theory will be |
Planar triangle
Pyramidal
Tetrahedral
Square planar
|
20 |
H-bonding is not present in |
Glycerine
Water
Hydrogen sulphide
Hydrogen fluride
|
21 |
The structure of ICI2is |
Trigonal
Trigonal bipyramidal
Octahedral
Square planar
|
22 |
Which of the following species is paramagnetic? |
CO<sub>2</sub>
NO
O<sup>2-</sup>
CN
|
23 |
The nature of interparticle forces in benzene is |
Dipole-dipole interaction
Dispersion force
Ion-dipole interaction
H-bonding
|
24 |
A molecule in which sp2hybrid orbitals are used by the central atom in forming covalent bonds in |
He<sub>2</sub>
SO<sub>2</sub>
PCl<sub>5</sub>
N<sub>2</sub>
|
25 |
Which of the following has unchanged valency? |
H
Na
Fe
Oxygen
|
26 |
Which of the following phenomena will occur when two atoms of the elements having same spin of electron approach for bonding? |
Orbital overlap will not occur
Bonding will not occur
Both (A) and (B) are correct
None of the above are correct
|
27 |
Which one of these is weakest? |
Ionest bond
Covalent bond
Metallic bond
Van der Waal's forces
|
28 |
XeF4has shape of |
Sphere
Trigonal bipyramidal
Tetrahedral
Square planar
|
29 |
Inter molecular forces in solid hydrogen are |
Covalent forces
Van der Waal forces or London dispersion forces
Hydrogen bonds
All of these
|
30 |
According to MO Theory, the species O2+ possesses |
bond order of 2.5
three unpaired
diamagnetic character
stability lower then O<sub>2</sub>
|