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ECAT Chemistry Chapter 5 Atomic Structure Online Test MCQs With Answers
Question # 1
In the atomic emission spectrum the lines which appear bright, appear dark in absorption spectrum because
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The radiations emitted in emission spectrum are absorbed in absorption spectrum
Atomic emission spectrum is continuous
Atomic absorption spectrum is continuous
Distance between the lines increases
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Question # 2
The maximum number of electrons in a subshell for which l = 3 is
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14
10
8
4
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Question # 3
If the value of azimuthal quantum number is 3, then values of m the magnetic quantum no. will be
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0, 1, 2, 3
+3, +2, +1, -1, -2, -3
0, -1, -2 ,-3
-3, 0, +3
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Question # 4
Find the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25
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3.0 BM
4.9 BM
5.9 BM
6.9 BM
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Question # 5
In the ground state of an atom the electron is present
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In the nucleus
In the second shell
Nearest to the nucleus
Farthest from the nucleus
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Question # 6
Pauli's principle is applicable to
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Degenerate orbits
Two electrons in the same orbital
One electron
None
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Question # 7
Cathode rays drive a small paddle wheel placed in their path. This observation shows that
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Cathode rays travel in straight lines
Cathode rays are negatively charged
Cathode rays produce x-rays
Cathode rays are material particles having momentum
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Question # 8
The velocity of photon is:
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Independent of its wavelength.
Depends on its wavelength.
Equal to square of its amplitude
Depends on its source.
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Question # 9
If the radius of first Bohr orbit be a
o
, then the radius of third Bohr orbit would be
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3 x a
o
6 x a
o
9 x a
o
1/2 x a
o
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Question # 10
The atomic number of an element is 35 what is the total number of electrons present in all the p-orbitals of the ground state atom of that element?
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6
11
17
23
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Question # 11
Negatively charged particle nature of cathode rays was first demonstrated in 1895 by:
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Millikan.
J. Perrin.
Hittrof
J.J. Thomson.
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Question # 12
For a 3P subshell the set of principle and azimuthal quantum number is
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n = 1 , l = 2
n = 3, l = 0
n = 3, l = 1
n = 1, l = 3
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Question # 13
Heaviest particle is
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Meson
Neutron
Proton
Electron
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Question # 14
The value of charge on electron is
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1.602 x 10
-19
coulombs
1.602 x 10
-18
coulombs
1.602 x 10
-17
coulombs
1.602 x 10
-16
coulombs
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Question # 15
When potassium metal is exposed to violet light
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Ejection of electrons takes place
Ejection of some potassium atoms occurs
There is no effect
The absorption of electrons takes place
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Question # 16
The wave number of the line emitted is 109.678 x 10
5
m
-1
in the Lyman series when electron transition occurs
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Question # 17
Orbital having same energy is called:
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Hybrid orbital.
Valence orbital.
Degenerate orbital.
D-orbital.
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Question # 18
The order of distance between the various Bohr orbits is
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r
2
- r
1
> r
3
- r
2
> r
4
- r
3
> ......
r
1
> r
2
> r
2
- r
3
> r
4
-r
3
> .....
r
2
-r
1
= r
3
- r
2
= r
4
- r
3
> .....
r
2
- r
1
> r
3
- r
2
< r
4
- r
3
< ....
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Question # 19
Which of the following was discovered first:
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Charge to mass ratio of electrons.
Mass of electrons.
Charge of electrons.
All of above at same time.
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Question # 20
Bohr model of atom is contradicted by:
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Planck's quantum theory
Pauli's exclusion theory
Heisenberg's uncertainty principle.
All of above.
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Question # 21
The range of visible spectrum is
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300 - 600 nm
600 - 900 nm
400 - 750 nm
100 - 300 nm
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Question # 22
In the ground state of an atom, the electron is present:
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In the nucleus.
In the second shell.
Nearest to the nucleus.
farthest from the nucleus.
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Question # 23
Which of the following is not charged particle
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Proton
Electron
Neutron
Hydrogen nucleus
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Question # 24
The four quantum numbers of the valency electron of potassium are
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4,1,1,1/2
4,0,0,1/2
4,1,0,1/2
4,4,0,1/2
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Question # 25
When 3p orbital is complete, the entering electron goes into
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4s
3d
4p
4f
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Question # 26
Which of the atoms has 1s
2
, 2s
2
, 2p
x
2
2p
1
y
2p
1
z
configuration
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Nitrogen
Carbon
Fluorine
Oxygen
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Question # 27
Neutron was discovered by:
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Chadwick.
Bohr.
Rutherford.
Plank.
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Question # 28
In the ground state of an atom, the electron is present
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In the nucleus
In the second shell
Nearest to the nucleus
Farthest from the nucleus
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Question # 29
With increasing principle quantum number, the energy difference between adjacent energy levels in H atom
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Decreases
Increases
Remains constant
Decreases for low value of Z and increase for higher value of Z
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Question # 30
The principle quantum number describes
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The distance form the nucleus
The shape of the orbital
The orientation of the orbital
The spin of the electron
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Question # 31
No cathode rays are produced in the discharged tube when gas is under ordinary pressure even if voltage of 5000 to 10000 is applies. This reason is
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Voltage is low
Discharge tube is not coloured
Gas does not conduct current under ordinary pressure
Temperature low
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