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ECAT Chemistry Chapter 5 Atomic Structure Online Test MCQs With Answers
Question # 1
With increasing principle quantum number, the energy difference between adjacent energy levels in H atom
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Decreases
Increases
Remains constant
Decreases for low value of Z and increase for higher value of Z
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Question # 2
Subsidiary quantum number specifies
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size of orbital
shape of orbital
orientations of orbitals
Nuclear stability
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Question # 3
Four d-orbitals contain four lobes while fifth contains only two lobes the orbital is
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dxy
dxz
dz
2
dx
2
- y
2
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Question # 4
The ratio of the ionization energy of H and Be
3+
is
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1 : 1
1 : 3
1 : 9
1 : 16
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Question # 5
Splitting of spectral lines of the hydrogen atom under the influence or magnetic field is called
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Stark effect
Zeeman effect
Compton effect
Photoelectric effect
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Question # 6
A 4f orbital has
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one node
two node
three node
four nodes
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Question # 7
When 6d orbital is complete, the entering electron goes into:
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7f.
7s.
7p.
7d.
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Question # 8
Maximum potential energy that an electron can have within the atom is:
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Equal to zero.
Less than zero.
Greater than zero.
Infinite
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Question # 9
The radius of first orbit of H-atom is
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4.75 A°
3.84 A°
8.4 A°
0.529 A°
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Question # 10
The order of frequency of the following radiations unltraviolet, visible, infrared and microwave is
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Microwave > infrared > visible > ultraviolet
Visible > ultraviolet > microwave > infrared
Ultraviolet > visible > infrared > microwave
Infrared > microwave > ultraviolet > visible
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Question # 11
Negatively charged particle nature of cathode rays was first demonstrated in 1895 by:
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Millikan.
J. Perrin.
Hittrof
J.J. Thomson.
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Question # 12
The atomic number of an element is 35 what is the total number of electrons present in all the p-orbitals of the ground state atom of that element?
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6
11
17
23
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Question # 13
Energy of electron in the infinite Bohr orbit of H-atom is
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0 KJ/mole
1 KJ/mole
-1 KJ/mole
-1313.32 KJ/mole
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Question # 14
The configuration 1s
2
2s
2
2p
5
3s
1
shows
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Excited state of O
2
Excited state of neon
Excited state of fluorine
Ground state of fluorine atom
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Question # 15
Rutherford's atomic model suggests the existence of
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Atom
Nucleus
alpha particle
Measons
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Question # 16
When the electron jumps form third, fourth, fifth orbits to the second orbit, the transitions are known as
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Paschen
Pfund
Balmer
Brackett
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Question # 17
The value of Plank's constant 'h' is
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6.625 x 10
-34
6.625 x 10
-34
J sec
6.625 x 10
-34
KJ
6.625 x 10
-34
K Cal
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Question # 18
Sodium chloride imparts a yellow colour to the Bunsen flame. This can be interpreted due to the
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low ionization energy of sodium
sublimation of metallic sodium to give yellow vapour
emission of excess energy absorbed as a radiation in the visible region as a radiation in the visible region
photosenitivity
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Question # 19
An electron with n = 3 , l = 2 will be in the sub-shell
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3p
3d
3f
3s
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Question # 20
Quantum number value for 2p orbitals are:
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n=2 ,l=1
n=1 ,l=2
n= ,l=0
n=2 ,l=0
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Question # 21
Which is not true with respect to cathode rays?
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A stream of electrons
Charged particles
Move with speed as that of light
Can be deflected by magnetic fields
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Question # 22
Charge on electron was discovered by:
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Millikan.
Crook.
Neil Bohr.
Rutherford.
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Question # 23
Effective magnetic moment of Sc
3+
ion is
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1.73
0
5.92
2.83
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Question # 24
When 6s orbital is complete then next electron goes to
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6p
6d
5d
4f
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Question # 25
Anode is the surface on which probability of finding electron is:
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50%
Less than 10%.
More than 95%.
Zero.
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Question # 26
Charge to mass ratio of electron was discovered by:
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Millika.
Rutherford.
J.J. Thomson.
Chadwick.
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Question # 27
In Bohr model of hydrogen atom the distance between adjacent orbits increases away from the nucleus, the energy difference between the orbits
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Increases
Decreases
Reaming same
Orbits coincide
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Question # 28
Which one of the following particles has amass 1/1836 time, that of hydrogen?
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Neutron.
Proton.
Electron.
Positron.
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Question # 29
Cathode rays emitted from cathode are
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Canal rays
Protons
Electrons
Positrons
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Question # 30
Bohr model of atom is contradicted by:
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Planck's quantum theory
Pauli's exclusion theory
Heisenberg's uncertainty principle.
All of above.
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Question # 31
The nature of the positive rays depend on
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The nature of the electrode
The nature of the discharge tube
The nature of the residual gas
All of the above
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