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ECAT Chemistry Chapter 5 Atomic Structure Online Test MCQs With Answers
Question # 1
For a 3P subshell the set of principle and azimuthal quantum number is
Choose an answer
n = 1 , l = 2
n = 3, l = 0
n = 3, l = 1
n = 1, l = 3
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Question # 2
Splitting of spectral lines when atoms are subjected to strong electron field is called
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Zeeman effect
Stark effect
Photoelectric effect
Compton effect
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Question # 3
When potassium metal is exposed to violet light
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Ejection of electrons takes place
Ejection of some potassium atoms occurs
There is no effect
The absorption of electrons takes place
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Question # 4
In Millikan method for determination of charge on electron the air in the chamber is ionized by
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Protons
Electric field
X-rays
a - particles
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Question # 5
Bohr model of atom is contradicted by:
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Planck's quantum theory
Pauli's exclusion theory
Heisenberg's uncertainty principle.
All of above.
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Question # 6
Which of the following was discovered first:
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Charge to mass ratio of electrons.
Mass of electrons.
Charge of electrons.
All of above at same time.
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Question # 7
An orbital can accommodate maximum two electrons with opposite spins according to
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Heisenberg's principle
Aufbau principle
Hund's srule
Pauli exclusion principle
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Question # 8
The nature of the positive rays depend on
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The nature of the electrode
The nature of the discharge tube
The nature of the residual gas
All of the above
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Question # 9
The quantum number which describe the orientation of the orbitals is
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Spin quantum number
Principle quantum number
Azimathal quantum number
Magnetic quantum number
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Question # 10
The limiting line of Blamer series in hydrogen spectrum lies in
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Visible regions
Ultraviolet region
Infrared region
x-rays region
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Question # 11
Negatively charged particle nature of cathode rays was first demonstrated in 1895 by:
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Millikan.
J. Perrin.
Hittrof
J.J. Thomson.
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Question # 12
The energy of ionization of an atom is the energy difference between orbital
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Question # 13
Alpha rays consist of:
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Neutrons.
Helium nucleus.
Protons.
Hydrogen nucleus.
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Question # 14
Maximum potential energy that an electron can have within the atom is:
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Equal to zero.
Less than zero.
Greater than zero.
Infinite
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Question # 15
With increasing principle quantum number, the energy difference between adjacent energy levels in H atom
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Decreases
Increases
Remains constant
Decreases for low value of Z and increase for higher value of Z
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Question # 16
Electrons arranged in orbitals according to the increasing order of their n + l values, this rule is named as
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Hund's rule
Heisenberg's principle
Paulit exclusion principle
Auf bau principle
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Question # 17
In the atomic emission spectrum the lines which appear bright, appear dark in absorption spectrum because
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The radiations emitted in emission spectrum are absorbed in absorption spectrum
Atomic emission spectrum is continuous
Atomic absorption spectrum is continuous
Distance between the lines increases
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Question # 18
The total number of orbitals possible for the quantum number n is
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n
n
2
2n
2n
2
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Question # 19
Orbital having same energy is called:
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Hybrid orbital.
Valence orbital.
Degenerate orbital.
D-orbital.
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Question # 20
The total number of possible values of magnetic quantum number for the value of l=3 is
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3
1
5
7
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Question # 21
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Neutrons are attracted by nucleus
Neutrons carry out nuclear reactions
Neutrons carry no charge
Neutrons are electromagnetic radiations
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Question # 22
Rutherford's atomic model suggests the existence of
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Atom
Nucleus
alpha particle
Measons
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Question # 23
The electronic configuration of an atom/ion can be defined by the following
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Aufbau principle
Pauli's exclusion principle
Hund's Rule
All the above
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Question # 24
A 4f orbital has
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one node
two node
three node
four nodes
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Question # 25
For principle quantum number n=4, the total number of orbitals having l = 3 is
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3
7
5
9
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Question # 26
The energy of the first electron is helium will be
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-13.6 eV
-54.4 eV
-5.44 eV
zero
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Question # 27
Subsidiary quantum number specifies
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size of orbital
shape of orbital
orientations of orbitals
Nuclear stability
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Question # 28
Which of the following orbitals have a dumb bell shape?
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s
p
d
f
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Question # 29
Orbitals having same energy are called
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Hybrid orbitals
Valence orbitals
Degenerate orbitals
D-orbitals
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Question # 30
For which of the following sets of quantum numbers and electron will have the highest energy?
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3,2,1,1/2
4,2,-1,1/2
4,1,0,-1/2
5,0,0,1/2
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Question # 31
Charge to mass ratio (e/m) of the electron is determined by
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R. A. Millikan
J. J. Thompson
G. J, Stoney
None of these
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