1 |
Lactic acid on oxidation by alkaline potassium permanganate gives |
Tartaric acid
Pyruvic acid
Cinnamic acid
Propionic acid
|
2 |
Hydrolysis of an ester gives a carboxylic acid which on Kolbe's electrolysis yields ethane. the easter is |
Ethyl methonoate
Methyl ethanoate
Propylamine
Ethylamine
|
3 |
HCOOH reacts with conc. H2SO4to produce |
CO
CO<sub>2</sub>
NO
NO<sub>2</sub>
|
4 |
When propanamide reacts with Br2and NaOH then which of the following compounds is formed? |
Ethyl alcohol
Propyl alcohol
Propyl amine
Ethylamine
|
5 |
Hydrolytic reaction of fats by causic soda is known as |
Acetylation
Carboxylation
Esterification
Saponification
|
6 |
What will happen if LiAIH4is added to an ester? |
Two units of alcohol are obtained
One unit of alcohol and one unit of acid is obtained
Two units of acids are obtained
None of these
|
7 |
Rearrangement of an oxime to an amide in the presence of strong acid is called |
Curtius rearrangement
Fries rearrangement
Beckman rearrangement
Aldol condensation
|
8 |
Which of the following reagents is used to distinguish between methanoic acid and ethanoic acid? |
Amm. silver nitrate solution
Neutral ferric chloride
Sodium hydroxide solution
Sodium carbonate solution
|
9 |
Rosenmund's reduction of an acyl chloride gives |
An aldehydes
An alcohol
An ester
A hydrocarbon
|
10 |
Which of the following compounds on boiling with KMnO4(alk) and subsequent acidification will not give benzoic acid? |
Benzyl alcohol
Acetophenone
Anisole
Toluene
|
11 |
Saponification of ethyl benzoate with caustic soda |
Benzyl alcohol,ethanoic acid
Sodium benzoate, ethanol
Benzoic acid, sodium ethoxide
Phenol, ethanoic acid
|
12 |
Ethyl acetate reacts with CH3MgBr to form |
Secondary alcohol
Tertiary alcohol
Primary alcohol and acid
Acid
|
13 |
Lower carboxylic acids are soluble in water due to |
Low molecular weight
Hydrogen bonding
Dissociation into ions
Easy hydrolysis
|
14 |
Hydrolysis of trichloromethane with aqueous KOH gives |
Potassium formate
Acetylene
Chloral
Methanol
|
15 |
If acetyl chloride is reducing in the presence of BaSO4and Pd, then |
CH<sub>3</sub>CHO is formed
CH<sub>3</sub>CH<sub>2</sub>OH is formed
CH<sub>3</sub>COOH is formed
CH<sub>3</sub>COCH<sub>3</sub>is formed
|
16 |
Which of the following is the strongest acid? |
CF<sub>3</sub>COOH
CBr<sub>3</sub>COOH
CH<sub>3</sub>COOH
CCl<sub>3</sub>COOH
|
17 |
The order of decreasing ease of reaction with ammonia is |
Anhydrides, esters, ethers
Anhydrides, ethers, esters
Ethers, anhydrides, esters
Esters, ethers, anhydrides
|
18 |
The acid showing salt like character in aqueous solution is |
Acetic acid
Benzoic acid
Formic acid
<span style="color: rgb(34, 34, 34); font-family: arial, sans-serif; font-size: small;">α - Aminoacetic acid</span>
|
19 |
In the presence of Aluminium ethoxide, aldehydes get converted into esters. The reaction is known as |
Schmidt reaction
Aldol condensation
Beckmann's rearrangement reaction
Tischenko reaction
|
20 |
A colourless liquid, at room temperature reacts with soda lime to form sodium salt of carboxylic acid and ammonia gas. The liquids is |
Propanamide
Propanoic acid
Formamide
Methyl Ethanoate
|
21 |
Lactic acid on heating with dil. H2SO4gives |
Acetic acid
Propionic acid
Acrylic acid
Formic acid
|
22 |
From the following values of dissociation constants of four acids which value represents the strongest acid? |
2 x 10<sup>-2</sup>
0.02 x 10<sup>-1</sup>
3 x 10<sup>-4</sup>
2 x 10<sup>-4</sup>
|
23 |
Acyl halide is formed by reacting PCl5with |
Alcohol
Ester
Amide
Both carboxylic acids as well as esters
|
24 |
Which of the following order is incorrect w.r.t property indicated? |
Formic acid > Acetic acid > Propionic acid (ACID STRENGTH)
Cyclohexanol < Phenol < Benzoic acid ( ACID STRENGTH)
Benzamide < Aniline < Cyclohexylamine ( ACID STRENGTH)
FCH<sub>2</sub>COOH > CICH<sub>2</sub>COOH > BrCH<sub>2</sub>COOH (ACID STRENGTH)
|
25 |
What is formed when oxalic acid is dehydrated by conc. H2SO4? |
C + CO<sub>2</sub>
CO
CO<sub>2</sub>
CO + CO<sub>2</sub>
|
26 |
Acetamide and NaOBr/OH-produce |
Ethanamine
Methanamide
CH<sub>3</sub>CN
NH<sub>3</sub>
|
27 |
Acidic hydrolysis of acetamide gives |
Acetaldehyde
Acetic acid
Methyl amine
Formic acid
|
28 |
Acetamide is |
Highly acidic
Highly basic
Neutral
amphoteric
|
29 |
Ethyl alcohol reacts with acetyl chloride to form |
Ethyl chloride
Acetic acid
Methyleacetate
Ethyleacetate
|
30 |
Weakest acid among the followings is |
Acetic acid
Phenol
Water
Acetylene
|