1 |
Which one of the following reagents will distinguish between C6H5CHO and C6H5COCH3 |
Aqueous bromine
Phosphorus pentachloride
2, 4 DNPH
Tollen's reagent
|
2 |
Aldelydes are the oxidation product of |
P-alcohols
s-alcohols
ter-alcohols
carboxylic acids
|
3 |
The color of ppts formed by Benedirct's test is |
Brick red
Wine red
Yellow
Orange
|
4 |
Which of the following compounds will react with Tollen's reagent |
|
5 |
The catalytic prmoter used for the industrial preparation of acetaldehyde is |
PdCI<sub>2</sub>
CuCI<sub>2</sub>
Pd + CaCI<sub>2</sub>
None of these
|
6 |
Acetone reacts with HCN to form a cyanohydrin. It is an example of |
Electrophilic addition
Electrophilic substitution
Nucleophilic addition
Nucleophilic substitution
|
7 |
Ketones are prepared by the oxidation of |
Primary alcohol
Secondary alcohol
Tertiary alcohol
None of these
|
8 |
Which of the following will have the highest boiling point |
Methanol
Ethanol
Propanal
2-hexanone
|
9 |
Which of the following is halo form |
CHBr<sub>3</sub>
CHCI<sub>3</sub>
CHI<sub>3</sub>
All of these
|
10 |
The carbon atom of a carbonyl group is |
Sp hybridized
Sp<sup>2</sup>hybridized
Sp<sup>3</sup>hybridized
None of these
|
11 |
Which is used for the reduction of aldehydes and ketones |
NaBH<sub>4</sub>
Pt/Pd
Ni
All of these
|
12 |
Ketones are reduced to |
Primary alcohol
Secondary alcohol
Tertiary alcohol
All of these
|
13 |
Aldehydes can be distinguished from ketones by |
2,4-DNPH test
NaHSO<sub>3</sub>test
N<sub>2</sub>H<sub>4</sub>test
Tollen's test
|
14 |
The colour of ppts formed by Fehling's test is |
Brick red
Red
Yellow
Orange
|
15 |
Aldehyde and small methyl ketones form crystalline ______ ppts with saturated sodium bisulphate solution |
White
Red
Yellow
None of these
|
16 |
In Tolten's best, the end product is ______ formed |
White ppts
Red ppts
Yellow ppts
Silver mirror
|
17 |
|
Treatment with HCN followed by acid hydrolysis
Oxidation of acetaldehyde followed by basic hydrolysis
Treatment with HCN followed by reduction
Treatment with HCN followed by oxidation
|
18 |
Distillation of calcium salts of acetic acid and formic acids gives acetaldehyde. What compound would be obtained if only calcium salt of acetic acid is distilled |
Formaldehyde
Butyraldehyde
Propionaldehyde
Acetone
|
19 |
Chromic acid used to oxidize |
Aldehyde
Ketone
Both a and b
None of these
|
20 |
|
2-chlorobutanal
alfa-chlorobutanal
2-chlorobutyraldehyde
alfa- chlorobutyraldehyde
|