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ECAT Chemistry Chapter 21 Alkyl Halides Online Test MCQs With Answers
Question # 1
In a primary alkyl halide, the halogen atom is attached to a carbon which is further attached to
Choose an answer
Only one carbon atom
Two carbon atoms
Three carbon atoms
one or no carbon atom
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Question # 2
On warming with silver powder,chloroform is converted into
Choose an answer
Acetylene
Hexachloroethane
1,1,2,2-tetrachloroethane
ethylene
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Question # 3
When an alcohol reacts with SOCI
2
an alkyl halide is formed. What are two other products
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SO
2
and HCI
SI
2
and H
2
O
HCI and H
2
O
H
2
S and HCI
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Question # 4
Choose an answer
Primary alkyl halide
Secondary alkyl halide
Tertiary alkyl halide
None of these
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Question # 5
Among the following the most reactive towards alcoholic KOH is
Choose an answer
CH
2
= CHBr
CH
3
COCH
2
CH
2
Br
CH
3
CH
2
Br
CH
3
CH
2
CH
2
Br
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Question # 6
What happens when CCl
4
is treated with AgNO
3
solution?
Choose an answer
NO
2
will be evolved
A white ppt. of AgCl will form
CCl
4
will dissolve in AgNO
3
solution
Nothing will happen
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Question # 7
Choose an answer
NH
3
HCl
KCN in C
2
H
5
OH NaOH
KCN in C
2
H
5
OH HCl
HCN NaOH
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Question # 8
Action of Zn with alkyl halides in the presence of an inert solvent forms higher alkanes. This reaction is known as
Choose an answer
Wurtz reaction
Frankland's reaction
Cannizaro reaction
Kalobe's reaction
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Question # 9
To get DDT, chlorobenzene has to react with one of the following compound in the presence of conc.H
2
SO
4
Choose an answer
Trichloroethane
Dichloroacetone
Dichloroacetaldehyde
Trichloroacetealdehyde
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Question # 10
Carbon atom holding halogen in aryl halides is
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sp
2
-hybridesed
sp
3
-hybridesed
sp-hybridesed
sp
3
d-hybridesed
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Question # 11
Dehydrohalogenation of alkyl halides produces
Choose an answer
Alcohol
Alkane
Alkene
Alkyne
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Question # 12
When primary amine reacts with chloroform in ethanolic KOH, then the product is
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An isocyanide
An aldehyde
A cyanide
An alcohol
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Question # 13
Grignard's reagent on treatment with carbonyl compounds yield
Choose an answer
Pheonol
Alcohol
Alkane
None of these
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Question # 14
The rate of E
1
reaction depends upon:
Choose an answer
The concentration of substrate
The concentration of nucleophile
The concentration of substrate as well as nucleophile
None of these
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Question # 15
Hydrolysis of Grignard's reagent gives:
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Alkane
Alkyl
Halide
Alcohol
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Question # 16
When metallic sodium in ether is heated with ethyl chloride, which alkane is formed
Choose an answer
Propane
Ethane
Iso-butane
N-butane
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Question # 17
Alkyl halides ae considered to be very reactive compounds towards nucleophiles because
Choose an answer
They have an electrophilic carbon
They have an electrophilic carbon and a good leaving group
They have an electrophilic carbon and a bad leaving group
They have a nucleophilic carbon and a good leaving group
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Question # 18
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF
2
Cl.
Choose an answer
CHF Cl C FCl
CH Cl CF
2
Cl
CHF CF
2
Cl
C FCl CF
2
Cl
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Question # 19
Choose an answer
Condensation
Electrophilic substitution
Free radical substitution
Nucleophilic substitution
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Question # 20
The general formula of alkyl halides is
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C
n
H
2n
X
C
n
H
2n-1
X
C
n
H
2n+1
X
C
n
H
2n-2
X
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Question # 21
Which represents nucleophilic aromatic substitution reaction?
Choose an answer
Reaction of benzene with Cl
2
in sunlight
Benzyl bromide hydrolysis with water
Reaction of NaOH with dintrofluoro benzene
Sulphonation of benzene
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Question # 22
If ketone reacts with Grignard's reagent, it also produces alcohol, But it will be a
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primary alcohol
Secondary alcohol
Tertiary alcohol
Aromatic alcohol
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Question # 23
2-Bromopentane is heated with potassium ethoxide in ethanol . The major product obtained is
Choose an answer
2-Ethoxypentane
Pent-1-ene
cis-Pent-2-ene
trans-Pent-2-ene
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Question # 24
Which one of the following is not a nucleophile
Choose an answer
H
2
O
H
2
S
BF
3
NH
3
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Question # 25
Ethyl chloride on treatment with aqueous alkali gives
Choose an answer
Ethane
Ethene
Ethanal
Ethanol
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Question # 26
Choose an answer
Electrophilic substitution
Free radical reduction
Isomerisation
Nucleophilic substitution
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Question # 27
Which of the followings is not a nulceophile
Choose an answer
OH
-
NH
3
C
2
H
5
O
-
Br
2
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Question # 28
When ethyl iodide and n-propyl iodide are allowed to react with sodium metal in ether, the number of alkanes that could be produced is
Choose an answer
Only one
Two alkanes
Three alkanes
Four alkanes
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Question # 29
Reduction of alkyl halides give
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Alkanes
Alkenes
Ketones
Ether
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Question # 30
Halogens on treating with silver salts of acids give
Choose an answer
Alcohol
Ester
Phenol
Alkyl halide
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Question # 31
Reaction of Griganard's reagent with CO
2
gives:
Choose an answer
Aldehyde
Pri-alcohol
Sec-alcohal
Carboxylic acid
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