1 |
Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of |
Onsolubility
Instability
Inductive effect
Steric hindrance
|
2 |
Which of the following compounds gives trichoromethane on distilling with bleaching power? |
Methanal
Phenol
Ethanol
methanol
|
3 |
Which represents nucleophilic aromatic substitution reaction? |
Reaction of benzene with Cl<sub>2</sub>in sunlight
Benzyl bromide hydrolysis with water
Reaction of NaOH with dintrofluoro benzene
Sulphonation of benzene
|
4 |
Which responds to +ve iodoform test? |
Butanol-1
Butan-1-al
Butanol-2
2-pentanone
|
5 |
Among the following the most reactive towards alcoholic KOH is |
CH<sub>2</sub>= CHBr
CH<sub>3</sub>COCH<sub>2</sub>CH<sub>2</sub>Br
CH<sub>3</sub>CH<sub>2</sub>Br
CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>Br
|
6 |
Allyl chloride on dehydrochlorination gives |
Propadiene
Propylene
Allyl alcohol
Acetone
|
7 |
When chloroform is boiled with NaOH, it gives |
Formic acid
Trihydroxymethane
Acetylene
Sodium formate
|
8 |
A set of compounds in which reactivity of halogen atom in the ascending order is |
Chlorobenzene, vinyl chloride, chloroethane
Chloroethane, chlorobenzene, vinyl chloride
Vinyl chloride,chlorobenzene chloroethane
Vinyl chloride, chloroethane,chlorobenzene
|
9 |
Most reactive halide towards SN1 reaction is |
n-Butyl chloride
sec-Butyl chloride
tert-Butyl choride
Allyl chloride
|
10 |
Grignard reagent is not prepared in aqueous medium but prepared in ether medium because |
The reagent is highly reactive in ether
The reagent does not react with water
The reagent becomes inactive in water
The reagent reacts with water
|
11 |
When primary amine reacts with chloroform in ethanolic KOH, then the product is |
An isocyanide
An aldehyde
A cyanide
An alcohol
|
12 |
Unpleasant smell of carbylamine is obtained when chloroform and alcoholic KOH are heated with |
Any aromatic amine
Any primary amine
Any amine
Any aliphatic amine
|
13 |
Which one of the following in mainly responsible for depletion of ozone layer? |
Methane
Carbon dioxide
Water
chloroflurocarbons
|
14 |
The reaction of an alkyl halide with RCOOAg produces |
Ester
Ether
Aldehyde
Ketone
|
15 |
On warming with silver powder,chloroform is converted into |
Acetylene
Hexachloroethane
1,1,2,2-tetrachloroethane
ethylene
|
16 |
Which one of the following will have the maximum dipole moment |
CH<sub>3</sub>F
CH<sub>3</sub>Cl
CH<sub>3</sub>Br
CH<sub>3</sub>l
|
17 |
Alkyl halides react with Mg in dry ether to form |
Magnesium halide
Grignard's reagent
Alkene
Alkyne
|
18 |
To get DDT, chlorobenzene has to react with one of the following compound in the presence of conc.H2SO4 |
Trichloroethane
Dichloroacetone
Dichloroacetaldehyde
Trichloroacetealdehyde
|
19 |
Cyanoform is ________ acid in nature than the chloroform. The missing word is |
Stronger
Weaker
Amphoteric
Neutral
|
20 |
Which halide among the following is used as methylating agent? |
CH<sub>3</sub>l
C<sub>2</sub>H<sub>5</sub>Cl
C<sub>2</sub>H<sub>5</sub>Br
C<sub>6</sub>H<sub>5</sub>Cl
|
21 |
How many monochlorobutanes will be possible on chlorination of n-butane? |
1
2
3
5
|
22 |
SN1 reaction of alkylhalides leads to |
Retention of configuration
Recemisation
Inversion of configuration
None of these
|
23 |
Tetrabromoethane on treatment with alcoholic zinc gives |
Ethylbromide
Ethane
Ethene
Ethyne
|
24 |
Gammexane is |
Chlorobenzene
Benzyl chloride
Brommobenzene
Benzene hexachloride
|
25 |
Benzene reacts with chlorine to form benzene hexachloride in presence of |
Nickel
AlCl<sub>3</sub>
Bright sunlight
Zinc
|
26 |
Ethyl bromide on treatment with alcoholic KOH gives |
Ethylene
Ethanol
Acetic Acid
Ethane
|
27 |
Butanenitrile is formed by reaction of KCN with |
Propyl alcohol
Butyl chloride
Butyl alcohol
Propyl Chloride
|
28 |
1-Chlorobutane on reaction with alcoholic potash gives |
But 1-ene
Butan-1-ol
But-2-ene
Butan-2-ol
|
29 |
2-Bromopentane is heated with potassium ethoxide in ethanol . The major product obtained is |
2-Ethoxypentane
Pent-1-ene
cis-Pent-2-ene
trans-Pent-2-ene
|
30 |
Chlorobenzene on heating with aqueous NH3under pressure in the presence of cuprous chloride gives |
Benzamide
Nitrobenzene
Aniline
Chloroaminobenzene
|