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ECAT Chemistry Chapter 21 Alkyl Halides Online Test MCQs With Answers
Question # 1
Grignard's reagent on treatment with chloramine give
Choose an answer
Acetamide
Primary amice
Secondary amice
Urea
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Question # 2
What is the total number of different chloroethanes, formula C
2
H
6-n
Cl
n
, where n can be any integer from 1 to 4
Choose an answer
4
6
7
8
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Question # 3
Reduction of alkyl halides give
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Alkanes
Alkenes
Ketones
Ether
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Question # 4
Benzene hexachloride is used as
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Dye
Antimaterial drug
Antibiotic
Insecticide
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Question # 5
Which reaction is example of nucleophilic substitution
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Question # 6
Grignard reagent is prepared by the reaction of magnesium metal with alkyl halide in the presence of
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Alcohol
Water
Suephuric acid
Dry ether
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Question # 7
Alkyl halides are considered to be very reactive compounds towards nucleophiles, because:
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They have an electrophilic carbon
They have an electrophilic carbon and good living gorup
They have an electrophilic carbon and bad living group
They have an nucleophilic carbon and good living gorup
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Question # 8
When an alcohol reacts with SOCI
2
an alkyl halide is formed. What are two other products
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SO
2
and HCI
SI
2
and H
2
O
HCI and H
2
O
H
2
S and HCI
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Question # 9
SN
2
reaction has order of reaction :
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First
Second
Third
Zero
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Question # 10
Iodoethane reacts with sodium in ether, the product formed is
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Pentene
Propyne
Butene
Butane
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Question # 11
Which of the following does not give iodoform test?
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Ethanol
Ethanal
Acetophenone
Bezophenone
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Question # 12
Any other aldehyde except formaldehyde on reaction with Grignard's will produce
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Secondary alcohol
Primary alcohol
Tertiary alcohol
Aromatic alcohol
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Question # 13
The compounds or species in search of electrons are called
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Elctrophiles
Nucleophile
Nitrities
Bases
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Question # 14
Which of the following alkyl halides is used as a mathylating agent
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CH
2
H
5
l
CH
3
l
C
2
H
5
Pr
C
2
H
5
Cl
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Question # 15
The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to
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4-Bromobenzyl cyanide
4-Cyanobenzyl chloride
4-Cyanobenzyle cyanide
4-Bromo 2-cyanobenzyl chloride
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Question # 16
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF
2
Cl.
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CHF Cl C FCl
CH Cl CF
2
Cl
CHF CF
2
Cl
C FCl CF
2
Cl
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Question # 17
1, 3-Dibromopropane reacts with metallic zinc to form
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Propene
Propane
Cyclopropane
Hexane
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Question # 18
Hydrolysis of Grignard's reagent gives:
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Alkane
Alkyl
Halide
Alcohol
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Question # 19
Grignard's reagent on treatment with carbonyl compounds yield
Choose an answer
Pheonol
Alcohol
Alkane
None of these
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Question # 20
Catalyst in the reaction ROH + SOCl
2
-------> RCL+SO
2
+HCl is:
Choose an answer
ZnCl
2
Pyridine
H
2
SO
4
Either
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Question # 21
Alkanes may be prepared by the reaction of alkyl halides with
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Alcohol
Carboxylic acid
Grignard reagents
None of these
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Question # 22
To get DDT, chlorobenzene has to react with one of the following compound in the presence of conc.H
2
SO
4
Choose an answer
Trichloroethane
Dichloroacetone
Dichloroacetaldehyde
Trichloroacetealdehyde
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Question # 23
What is the total number of different chloroethanes of formula C
2
H
6-n
Cl
n
possible (n may be 1 to 6)
Choose an answer
6
8
9
10
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Question # 24
Alkyl halides react with lithium dialkyl copper reagents to give
Choose an answer
Alkenes
Alkyl copper halides
Alkanes
Alkenyl halides
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Question # 25
Tetrabromoethane on treatment with alcoholic zinc gives
Choose an answer
Ethylbromide
Ethane
Ethene
Ethyne
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Question # 26
Which responds to +ve iodoform test?
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Butanol-1
Butan-1-al
Butanol-2
2-pentanone
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Question # 27
The alkyl halide is converted into an alcohol by
Choose an answer
Addition
Substitution
Dehydrohalogenation
Elimination
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Question # 28
The order of reactivity for a given halogen in Grignard's reagent is:
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CH
3
X > C
2
H
5
X > C
3
H
4
X > C
4
H
4
X
C
2
H
5
X > C
3
H
7
X > C
4
H
5
X > CH
4
X
C
3
H
7
X > C
4
H
7
X > CH
3
X > C
2
H
5
X
C
4
H
4
X > C
3
H
7
X > C
2
H
5
X > CH
4
X
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Question # 29
The order of reactivity of an alkyl halide (R-X) for a particular alkyl group is
Choose an answer
Iodide > bromide > chloride
Chloride > bromide > iodide
Bromide > chloride > iodide
Bromide > iodide > chloride
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Question # 30
When carbon dioxide is passed through the R - Mg - X is produced
Choose an answer
Any carboxylic acid
Propanoic acid
Propanedioic acid
None of these
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Question # 31
Replacement of Cl of Chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-Dinitrochlorobenzene is readily replaced because
Choose an answer
NO
2
makes the electron rich ring at ortho and para positions
NO
2
withdraws electrons at metaposition
NO
2
donate electrons at m-position
NO
2
withdraws electrons at ortho and para position
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