1 |
What is the total number of different chloroethanes, formula C2H6-nCln, where n can be any integer from 1 to 4 |
4
6
7
8
|
2 |
|
Condensation
Electrophilic substitution
Free radical substitution
Nucleophilic substitution
|
3 |
Each of the following compounds is effective as a refrigerant. The release of which one of these causes the greatest depletion of the ozone layer |
CCl<sub>2</sub>F<sub>2</sub>
CH<sub>3</sub>OCH<sub>3</sub>
CH<sub>3</sub>CHF<sub>2</sub>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
|
4 |
CFCs undergo homolytic fission by uv light in the stratosphere which radical could result from this irradiations of CHCICF2Cl. |
CHF Cl C FCl
CH Cl CF<sub>2</sub>Cl
CHF CF<sub>2</sub>Cl
C FCl CF<sub>2</sub>Cl
|
5 |
What is the total number of different chloroethanes of formula C2H6-nClnpossible (n may be 1 to 6) |
6
8
9
10
|
6 |
|
Electrophilic addition
Electrophilic substitution
Free radical substitution
Nuclophilic addition
|
7 |
Which one of the following is not a nucleophile |
H<sub>2</sub>O
H<sub>2</sub>S
BF<sub>3</sub>
NH<sub>3</sub>
|
8 |
Alkyl halides ae considered to be very reactive compounds towards nucleophiles because |
They have an electrophilic carbon
They have an electrophilic carbon and a good leaving group
They have an electrophilic carbon and a bad leaving group
They have a nucleophilic carbon and a good leaving group
|
9 |
When CO2is made to react with ethyl magnesium iodide, followed by acid hydrolysis, the product formed is |
Propane
Propanoic acid
Propanal
Propanol
|
10 |
Grignard's reagent is |
Alkyl halide
Magnesium halide
Alkyl magnesium halide
Ethereal solution of an alkyl halide
|
11 |
When formaldehyde is added to Grignard reagent we get |
Aldehyde
Acetone
Primary alcohol
Secondary alcohol
|
12 |
The compounds or species in search of electrons are called |
Elctrophiles
Nucleophile
Nitrities
Bases
|
13 |
Thre rate of SN2 reaction depends upon the |
Concentration of alkyl halides
Concentration of nucleophile
Concentration of alkyl halides and nucleophile
None of the above
|
14 |
When alkyl halide is heated with aqueous solution of ammonia at 100°C the major product is |
Primary amine
Secondary amine
Tertiary amine
Mixture of amines and salt
|
15 |
Which of the following alkyl halides is used as a mathylating agent |
CH<sub>2</sub>H<sub>5</sub>l
CH<sub>3</sub>l
C<sub>2</sub>H<sub>5</sub>Pr
C<sub>2</sub>H<sub>5</sub>Cl
|
16 |
The elimination of hydrogen halide from adjacent carbon atoms is called |
Dehydrogenation
Hydrogenation
Dehydrohalogenation
Hydrohalogenation
|
17 |
Ethyl bromide is formed by the reaction of HBr with |
Ethane
Ethene
Ethyne
Propane
|
18 |
A carbon atom carrying a postitive charge and attached to three other atoms of groups is called |
Caronium ion
Carbanion
Oconium ion
Carba ion
|
19 |
Alkyl halides in which a halogen atom is bonded to that carbon atom which directly bonded with one hydrogen atom is called |
Primary alkyl halides
Secondary alkyl halides
Tertiary alkyl halides
Quaternary alkyl halides
|
20 |
Which of the following compounds will form a hydrocarbon on reaction with Grignard reagent |
A ketone
An aldehyde
An ether
Water
|
21 |
Which of the following is a nucleophile |
OH
CH(CH<sub>3</sub>)<sub>3</sub>
CH<sub>3</sub><sup>+</sup>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
|
22 |
Any other aldehyde except formaldehyde on reaction with Grignard's will produce |
Secondary alcohol
Primary alcohol
Tertiary alcohol
Aromatic alcohol
|
23 |
If ketone reacts with Grignard's reagent, it also produces alcohol, But it will be a |
primary alcohol
Secondary alcohol
Tertiary alcohol
Aromatic alcohol
|
24 |
Alcohol can be prepared from Grignard's reagent with an aldehyde: If we start with formaldehyde the product alcohol with be |
Primary
Secondary
Territory
Aromatic
|
25 |
If carbon dioxide is bubbled through solution of Grignard's reagent in ether and the resultant product is reacted with hydrochloric acid, it gives |
An alkane
Al alcohol
A carboxylic acid
An aldehyde
|
26 |
If Grignard reagent is allowed to react with another alkyl halide the main product is |
An alkane
Cyclo alkane
Alkyne
An alkene
|
27 |
Ammonia like water also reacts with Grignard's reagent to give |
Alkane
Alkene
Alkyne
Amide
|
28 |
By simply reacting Grignand's reagent with water we get |
An alkane
Higher alkane
An alkene
An alkyne
|
29 |
Which of the following compounds could be prepared by reacting bromoethane with KCN and then reducing the product |
CH<sub>3</sub>CH<sub>3</sub>
CH<sub>3</sub>CH<sub>2</sub>NH<sub>2</sub>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>
CH<sub>3</sub>CH<sub>2</sub>CH<sub>3</sub>
|
30 |
In which of the following reactions is the inorganic reagent acting as a nucleophile |
|