1 |
When alkyl is treated with chlorine in the presence of sunlight |
1,3 dichloroproduct is formed
1,4 dichloro product is formed
1,3,5 trichloro product is formed
Only alkyl group is substituted
|
2 |
Which one does not declourized KMnO4 |
Alkenes
Alkynes
Bezene
All above
|
3 |
Substitution of halogen in the benzene ring requires catalyst |
AlCl<sub>3</sub>
FeCl<sub>3</sub>
SiO<sub>2</sub>
Organo - nickel
|
4 |
All are ortho & Para directing except |
X
OH
NR<sub>3</sub>
NH<sub>2</sub>
|
5 |
The difference between amount of heat actually released and that of calculated is called |
Bonding energy
Activation energy
Resonance energy
Transition energy
|
6 |
The three alternate single and double bonds in the benzene ring are called |
Conjugate bonds
Resonating bonds
Both A and B
None of above
|
7 |
The nitration of benzene takes place when it is heated with a mixture of conc.HNO3and conc. H2SO4at 50°C in ratio of |
1 : 2
1 : 1
1 : 3
2 : 1
|
8 |
The electrophile in aromatic sulphonation is |
H<sub>2</sub>SO<sub>4</sub>
HSO<sub>4</sub>
SO<sub>3</sub>
SO<sub>3</sub><sup>+</sup>
|
9 |
Which one of the following is (m-xylene) |
1,2 dimethyl benzene
1,3 dimethyl benzene
1,5 dimethyl benzene
1,4 dimethyl benzene
|
10 |
Benzene has a -------- structure |
Pentagonal
Hexagonal
Heptagonal
Tetragonal
|
11 |
Which of the following acid can be used as a catalyst in Friedal Craft's reactions |
AlCl<sub>3</sub>
HNO<sub>3</sub>
BeCl<sub>2</sub>
NaCl
|
12 |
Benzene does not undergo polymerization and it is also resistant to |
Reduction
Oxidation
Alkylation
Ozonolysis
|
13 |
Which class of compound is more reactive |
Alkane
Alkene
Alkyne
None
|
14 |
Meta directing group decreased the ----------- of benzene ring |
Physical activity
Chemical reactivity
Density
None
|
15 |
The electron releasing effect of methyl group is significant and it makes ring a good |
Electrophilic
Nucleophilic
Nucleophobic
Hydrophobic
|
16 |
How many isomeric disubtituted products are obtained by the introducing of second group in the ring |
Two
Three
Four
None
|
17 |
Alkyl benzenes are readily oxidized by axidfied |
KMnO<sub>4</sub>
K<sub>2</sub>CO<sub>3</sub>
MnO<sub>4</sub>
H<sub>2</sub>SO<sub>4</sub>
|
18 |
Benzene reacts with ozone and gives |
Glycerin
Glyoxal
Maleic anhydride
Benzoic acid
|
19 |
When benzene is burnt in free supply of air, it is completely oxidized to |
CO
CO<sub>2</sub><sub>+</sub>H<sub>2</sub>O
H<sub>2</sub>CO<sub>3</sub>
None
|
20 |
Sulphuric acid generates nitronium ion by reacting with |
Nitric acid
Nitrogen gas
Nitrous acid
Potassium nitrate
|
21 |
Which reaction is too vigorous to control |
Chlorination
Bromination
Iodination
Fluorination
|
22 |
Benzene is obtained from benzene sulphonic acid by treating with |
HCl
NaOH
H<sub>2</sub>O
NaHCO<sub>3</sub>
|
23 |
Benzene is not prepared from |
Acetylene
Phenol
Benzoic acid
Bromo benzene
|
24 |
The stability of acromatic compounds decreases with ------- in the no. of its resonance structure |
Decrease
Increase
Remain constant
Partially decreases
|
25 |
Hybridization of each carbon atom in benzene ring is |
sp hybridized
sp<sup>2</sup>hybridized
sp<sup>3</sup>
dsp<sup>2</sup>
|
26 |
A six membered ring containing one double bond called |
Cyclohexene
Cyclohexane
Cyclohexadiene
None
|
27 |
All C - H bond lengths of benzene ring is |
1.07A<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
1.09A<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
1.08A<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
None
|
28 |
The C-C bond angles in benzene ring are |
119<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
120<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
121<span style="color: rgb(84, 84, 84); font-family: arial, sans-serif; font-size: small;">°</span>
None
|
29 |
How many molecules of chlorine adds in benzene in the presence of sunlight |
One
Two
Three
Four
|
30 |
The empirical formula of benzene is determined by |
IR spectra
U.V
Elemental analysis
NMR spectra
|